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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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1865-7117
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Volume 38, Issue 9 (Sep 1983)

Issues

The Molecular Structure of Selenium Dichloride, SeCl2, Determined by Gas Electron Diffraction

Liv Fernholt
  • Department of Chemistry, University of Oslo, Box 1033, Blindern, Oslo 3, Norway
/ Arne Haaland
  • Department of Chemistry, University of Oslo, Box 1033, Blindern, Oslo 3, Norway
/ Ragnhild Seip
  • Department of Chemistry, University of Oslo, Box 1033, Blindern, Oslo 3, Norway
/ Rüdiger Kniep
  • Institut für Anorganische Chemie und Strukturchemie der Universität Düsseldorf
/ Lutz Korte
  • Institut für Anorganische Chemie und Strukturchemie der Universität Düsseldorf
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1983-0907

Abstract

The electron diffraction pattern of the vapor from a sample of SeCl4 has been recorded with a reservoir and nozzle temperature of about 175 °C. The gas jet was found to consist of SeCl2 (80%) and Cl2 (20%). The bond distance in SeCl2 is ra(Se-Cl) = 2.157(3) Å, the valence angle <ClSeCl = 99.6(5)°.

Keywords: Molecular Structure; Selenium(II) Chloride; Gas Electron Diffraction

About the article

Received: 1983-05-19

Published Online: 2014-06-02

Published in Print: 1983-09-01


Citation Information: Zeitschrift für Naturforschung B, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1983-0907. Export Citation

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. (CC BY-NC-ND 3.0)

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[1]
Ronald J. Gillespie and Edward A. Robinson
Angewandte Chemie, 1996, Volume 108, Number 5, Page 539
[2]
Magdolna Hargittai
Coordination Chemistry Reviews, 1988, Volume 91, Page 35

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