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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year

IMPACT FACTOR 2017: 0.757

CiteScore 2017: 0.68

SCImago Journal Rank (SJR) 2017: 0.277
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Volume 39, Issue 6


K2SiP2, ein Phosphidopolysilikat(IV) / K2SiP2, a Phosphidopolysilicate (IV)

Brigitte Eisenmann
  • Abt. II für Anorganische Chemie im E.-Zintl-Institut der TH Darmstadt, Hochschulstraße 4, D-6100 Darmstadt
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Mehmet Somer
  • Anorganisch-chemisches Institut der TU Clausthal, Paul-Ernst-Straße 4, D-3392 Clausthal-Zellerfeld
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1984-0607


The new compound K2SiP2 crystallizes in the orthorhombic system , space group Ibam. The unit cell with the lattice constants

a = 1292.6(6) pm, b - 686.7(4) pm, c - 610.7(4) pm

contains 4 formula units. In the structure SiP4 tetrahedra form chains by sharing common edges. The [(SiP2)2-] strings are isosteric to the SiS2 molecules.

Keywords: Phosphidopolysilicate; Crystal Structure

About the article

Received: 1983-02-03

Published Online: 2014-06-02

Published in Print: 1984-06-01

Citation Information: Zeitschrift für Naturforschung B, Volume 39, Issue 6, Pages 736–738, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1984-0607.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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