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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Bis[(η3-allyl)nickel(μ,η5-2,3-dihydro-1,3-diborolyl)]nickeI-Tetradecker- Komplexe mit terminalen Allylliganden/ Bis[(η3-allyl)nickel(μ,η5-2,3-dihydro-1,3-diborolyl)]nickel Tetradecker Complexes with Terminal Allyl Ligands

  • Thomas Kuhlmann and Walter Siebert

Abstract

Reactions between bis(allyl)nickel complexes and alkyl derivatives of 2,3-dihydro-1,3-diborole (1a, b) in refluxing toluene or mesitylene yield deeply colored solutions. By distillation and chromatography the first η3-allyl tetradecker complexes 8 were obtained in 4 -15% yield. In the violet residues higher molecular species are present, which could not be identified. The red, oily tetradeckers are characterized by NMR and mass spectra; their formation is discussed.

Received: 1984-3-10
Published Online: 2014-6-2
Published in Print: 1984-8-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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