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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2016: 0.631

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1865-7117
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Volume 40, Issue 1

Issues

Tetrahydrothiophen als Komplexligand; Darstellung und Charakterisierung von Spezies der Zusammensetzung M2(CO)9(C4H8S) (M = Mn, Re) und Mn2(CO)8(C4H8S). Röntgenstrukturanalysen von Mn2(CO)9(C4H8S) und Mn2(CO)8(C4H8S) / Tetrahydrothiophene as a Complex Ligand; Synthesis and Characterization of Species of Composition M2(CO)9(C4H8S) (M = Mn, Re) and Mn2(CO)8(C4H8S). X-Ray Structures of Mn2(CO)9(C4H8S) and Mn2(CO)8(C4H8S)

Ernst Guggolz
  • Anorg. Chem. Institut der Universität Heidelberg, Im Neuenheimer Feld 270, D-6900 Heidelberg 1
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/ Klaus Layer
  • Anorg. Chem. Institut der Universität Heidelberg, Im Neuenheimer Feld 270, D-6900 Heidelberg 1
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/ Franz Oberdorfer
  • Anorg. Chem. Institut der Universität Heidelberg, Im Neuenheimer Feld 270, D-6900 Heidelberg 1
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/ Manfred Ziegler
  • Corresponding author
  • Anorg. Chem. Institut der Universität Heidelberg, Im Neuenheimer Feld 270, D-6900 Heidelberg 1
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Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1985-0116

Heating of the decacarbonyls M2(CO)10 (M = Mn, Re) in tetrahydrothiophene under reflux gave the substitution products M2(CO)9(C4H8S) (M = Mn, Re) and Mn2(CO)8(C4H8S), respectively. In the former an equatorial CO group has been substituted, while in the latter the tetra- hydrothiophene ligand bridges symmetrically two Mn-Mn bonded Mn(CO)4 units. The manganese compounds (monoclinic, P21/c) were characterized by means of X-Ray structure analysis

: Synthesis; X-Ray; Decacarbonyl Derivatives

About the article

Received: 1984-11-06

Published Online: 2014-06-02

Published in Print: 1985-01-01


Citation Information: Zeitschrift für Naturforschung B, Volume 40, Issue 1, Pages 77–84, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1985-0116.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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