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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2016: 0.631

CiteScore 2017: 0.68

SCImago Journal Rank (SJR) 2017: 0.277
Source Normalized Impact per Paper (SNIP) 2017: 0.394

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1865-7117
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Volume 40, Issue 11

Issues

Unusual Quadrupole Splitting in D i- and Trialkylamine Substituted Pentacyanoferrate(II) Complexes

D. V. Parwate / A. N. Garg
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1985-1113

A series of pentacyanoferrate complexes, Na3[Fe(CN)5L] ·nH2O, where L = (CH3)2NH, (C2H5)2NH, (C2H5)3N, (C3H7)2NH, (C4H9)2NH, (C4H9)3N and (C6H5)2NH were studied by Mössbauer and infrared spectroscopy. All the complexes exhibited two line spectra with ⊿ EQ = 0.73-1.92 mms-1 and δ = −0.04−0.49 mms-1 (w.r.t. SNP) and can be divided into two groups with well defined parameters. Partial isomer shift and partial quadrupole splitting values were correlated with bonding characteristics.

Keywords: Pentacyanoferrate Complexes; Quadrupole Splitting

About the article

Received: 1985-05-28

Published Online: 2014-06-02

Published in Print: 1985-11-01


Citation Information: Zeitschrift für Naturforschung B, Volume 40, Issue 11, Pages 1495–1499, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1985-1113.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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