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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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IMPACT FACTOR 2016: 0.631

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1865-7117
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Volume 41, Issue 1

Issues

Transition Metal Squarates I. Chain Structures M (C4O4) · 4 H2O

Armin Weiss
  • Institut für Anorganische Chemie der Universität München, D-8000 München 2, Meiserstraße 1, Germany
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/ E. Riegler
  • Institut für Anorganische Chemie der Universität München, D-8000 München 2, Meiserstraße 1, Germany
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/ I. Alt
  • Institut für Anorganische Chemie der Universität München, D-8000 München 2, Meiserstraße 1, Germany
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/ H. Böhme
  • Institut für Anorganische Chemie der Universität München, D-8000 München 2, Meiserstraße 1, Germany
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/ Ch. Robl
  • Institut für Anorganische Chemie der Universität München, D-8000 München 2, Meiserstraße 1, Germany
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Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1986-0105

The transition metal squarates M(C4O4) · 4 H2O (M2+ = Mn2+, Fe2+, Co2+. Ni2+, and Zn2+) are isotypic. They crystallize monoclinically, space group Ce-Cf, and consist of one-dimensional chain molecules

[xxx]

with the chain axes alternatively in direction [110] and [110]. The transition metal is octahedrally coordinated by two oxygen atoms of two C4O42- -anions in rrarcs-position and 4 water molecules. Neighbouring chains are interlinked by hydrogen bonds. The distance between the planes of the parallel C4-rings of neighbouring chains is similar to the layer distance in graphite.

Keywords: Transition Metal Squarates. Chain Structures

About the article

Received: 1984-04-13

Published Online: 2014-06-02

Published in Print: 1986-01-01


Citation Information: Zeitschrift für Naturforschung B, Volume 41, Issue 1, Pages 18–24, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1986-0105.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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