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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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IMPACT FACTOR 2016: 0.631

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1865-7117
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Volume 41, Issue 1

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Beiträge zur Chemie des Bors, 168 [1] Synthese und Struktur von Azadiboriridinen / Contributions to the Chemistry of Boron, 168 [1] Synthesis and Structure of Azadiboriridines

Franz Dirschl
  • Institut für Anorganische Chemie der Universität München, Meiserstraße 1, D-8000 München 2
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/ Elisabeth Hanecker
  • Institut für Anorganische Chemie der Universität München, Meiserstraße 1, D-8000 München 2
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/ Heinrich Nöth
  • Institut für Anorganische Chemie der Universität München, Meiserstraße 1, D-8000 München 2
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/ Wilfried Rattay
  • Institut für Anorganische Chemie der Universität München, Meiserstraße 1, D-8000 München 2
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/ Walter Wagner
  • Institut für Anorganische Chemie der Universität München, Meiserstraße 1, D-8000 München 2
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Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1986-0107

Two representatives of the three membered B2N-ring system have been obtained by dehalogenation of diborylamines Me3CN[BHalNR2]2. In solution there is no restricted rotation at the exocyclic BN bond, even at low temperature. In contrast, the X-ray structure analysis of the bis-tetramethylpiperidino derivative 10a reveals alternation of short and long BN bonds; one of the tetramethylpiperidino groups stands nearly coplanar with the B2N-ring system, the other, however, is almost perpendicular to the ring plane. The ring contains a short BB bond (1.612 Å).

Keywords 1: -tert-Butyl-2.3-bis(diorganylamino)-1,2.3-azadiboriridine; X-Ray

About the article

Received: 1985-07-30

Published Online: 2014-06-02

Published in Print: 1986-01-01


Citation Information: Zeitschrift für Naturforschung B, Volume 41, Issue 1, Pages 32–37, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1986-0107.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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