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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2016: 0.631

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Source Normalized Impact per Paper (SNIP) 2016: 0.332

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1865-7117
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Volume 41, Issue 1

Issues

AsPh4[W(O)Cl3(HN3S2)]; Synthese, IR-Spektrum und Kristallstruktur / AsPh4[W(O)Cl3(HN3S2)]; Synthesis, IR Spectrum and Crystal Structure

Elke Conradi / Heribert Wadle / Ulrich Müller / Kurt Dehnicke
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1986-0110

Violet crystals of AsPh4[W(O)Cl3(HN3S2)] were obtained by partial hydrolysis of AsPh4[WCl4(N3S2)] in a saturated solution in CH2Cl2/CCl4. Its IR spectrum is reported. The crystal structure was determined by X-ray diffraction (2284 independent observed reflexions, R = 0.041). Crystal data: triclinic, space group P1̄, Z = 2, a = 812.2, b = 1268.4, c = 1343.9 pm, α = 88.58, β = 82.04 and γ = 88.26°. The compound consists of AsPh4 cations and [W(O)Cl3(HN3S2) anions in which the tungsten atoms have a distorted octahedral coordination with one oxo-ligand (171 pm), three chlorine atoms and two nitrogen atoms of the planar (HN3S7)2⊖ ligand. The WN bond lengths are 183 and 226 pm; the longer WN bond is due to the hydrogen atom attached to its N atom and to the trans influence of the oxo group. The crystal packing corresponds to one of the types frequently found among tetraphenylphosphonium compounds with cations stacked to parallel columns.

Keywords: Oxo-trichloro-hydrocyclothiazeno-tungstate(VI); Synthesis; IR Spectrum; Crystal Structure

About the article

Received: 1985-10-07

Published Online: 2014-06-02

Published in Print: 1986-01-01


Citation Information: Zeitschrift für Naturforschung B, Volume 41, Issue 1, Pages 48–52, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1986-0110.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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[1]
E. CONRADI, H. WADLE, U. MUELLER, and K. DEHNICKE
Chemischer Informationsdienst, 1986, Volume 17, Number 20
[2]
Paul F. Kelly, Alexandra M. Z. Slawin, David J. Williams, and J. Derek Woollins
Angewandte Chemie, 1992, Volume 104, Number 5, Page 620
[3]
Alfred Gieren, Catalina Ruiz-Pérez, Thomas Hübner, Max Herberhold, Klaus Schamel, and Karlheinz Guldner
Journal of Organometallic Chemistry, 1989, Volume 366, Number 1-2, Page 105

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