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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

[Fe(CO)4C(O)NMe2][C(NMe2)3]; die erste Strukturbestimmung einer Organometallverbindung mit dem Carbeniumion [C(NMe2)3]+/ [Fe(CO)4C(O)NMe2][C(NMe2)3]; the First Structure Determination on an Organometallic Compound with the Carbenium Ion [C(NMe2)3]+

  • Roland Boese , Dieter Bläser and Wolfgang Petz

Abstract

The crystal structure of the carbamoyl complex [(CO)4FeC(O)NMe2][C(NMe2)3] (1) is described. It crystallizes in the triclinic space group PI (a = 7.876(3), b = 10.098(3), c = 12.067(5)Å, α = 94.25(3), β = 90.94(3), γ = 97.30(3)°, Z = 2) and consists of independent ions. The cation has a planar CN3 array with sp2 hybridized C and N atoms. The carbamoyl group of the anion occupies an axial position in the trigonal bipyramidal environment of the iron atom.

Received: 1988-2-26
Revised: 1988-4-14
Published Online: 2014-6-2
Published in Print: 1988-8-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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