Abstract
2-Pyrryl-(m-terphenyl)-carbinol and 2-pyrryl-(3,3″,5.5″-tetra-t-butyl-m-terphenyl)-carbinol are cyclized in acidic medium to the corresponding raeso-tetraarylporphyrins. The meso-tetraarylporphyrins are transferred to the iron and manganese complexes. The reactions of the iron porphyrins with OH- are studied and the products of these reactions are characterized.
Keywords: meso-Tetraarylporphyrins; meso-Tetraarylporphinatoiron(III) Complexes. meso-Tetraarylporphinatomanganese(III) Complexes; meso-Tetraarylporphinatoiron(III) Hydroxides; (μ-Oxo-bis-(me50-tetraarylporphinatoiron(III))
Received: 1987-11-23
Published Online: 2014-6-2
Published in Print: 1988-8-1
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