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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences


IMPACT FACTOR 2017: 0.757

CiteScore 2017: 0.68

SCImago Journal Rank (SJR) 2017: 0.277
Source Normalized Impact per Paper (SNIP) 2017: 0.394

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1865-7117
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Volume 44, Issue 11

Issues

Darstellung von SCl2F+MF6~ (M = As, Sb) und zusammenfassende Betrachtung der Kationen SClnF3-n+ (n = 0-3) [1] / Preparation of SCl2F+MF6~ (M = As, Sb) and a Comprehensive Discussion of the Cations SClnF3-n+ (n = 0-3) [1]

Rolf Minkwitz
  • Universität Dortmund, Fachbereich Chemie, Anorganische Chemie, Postfach 500500, D-4600 Dortmund 50
  • Other articles by this author:
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/ Gabriele Nowicki
  • Universität Dortmund, Fachbereich Chemie, Anorganische Chemie, Postfach 500500, D-4600 Dortmund 50
  • Other articles by this author:
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Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1989-1102

The preparations and characterizations of compounds SCl2F+MF6~ (M = As, Sb) are reported. They are yellowish hydrolysable solids, with a strong tendency towards symmetrization in solution. The mass spectra data indicate the formation of SCl2F2 on thermolysis. The series of SClnF3-n+-cations (n = 0—3) is now complete, and a comprehensive discussion of the spectroscopic data is given.

About the article

Received: 1989-06-06

Published Online: 2014-06-02

Published in Print: 1989-11-01


Citation Information: Zeitschrift für Naturforschung B, Volume 44, Issue 11, Pages 1343–1347, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1989-1102.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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[1]
R. Minkwitz and W. Molsbeck
Zeitschrift f�r anorganische und allgemeine Chemie, 1992, Volume 612, Number 6, Page 35
[2]
R. Minkwitz, G. Nowicki, and H. Preut
Zeitschrift f�r anorganische und allgemeine Chemie, 1992, Volume 611, Number 5, Page 23
[4]
Valery K Brel, Namig Sh Pirkuliev, and Nikolai S Zefirov
Russian Chemical Reviews, 2001, Volume 70, Number 3, Page 231

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