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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2016: 0.631

CiteScore 2017: 0.68

SCImago Journal Rank (SJR) 2017: 0.277
Source Normalized Impact per Paper (SNIP) 2017: 0.394

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1865-7117
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Volume 46, Issue 2

Issues

Die Kristall- und Molekülstrukturen der Verbindungen [Cl4–xSn{Co(CO)4}x] mit x = 1,2 und 3 / The Crystal and Molecular Structures of the Compounds [Cl4-xSn{Co(CO)4}x] with x = 1,2 and 3

Peter Klüfers
  • Institut für Anorganische Chemie der Universität, Engesserstraße, Gebäude 30.45, D-7500 Karlsruhe 1
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Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1991-0211

The crystal structures of the compounds [Cl3SnCo(CO)4] 1, [Cl2Sn{Co(CO)4}2]2, and [ClSn{Co(CO)4}3]3, have been determined by X-ray crystallography. Sn is co-ordinated tetrahedrally by Cl- and Co-substituents, the co-ordination polyhedron of Co is a distorted trigonal bipyramid. The Sn -Cl- and the Sn-Co-distances both increase from 1 to 3 (Sn -Co: 247.7 in 1, 253.2 in 2, and 260.6 pm in 3).

Keywords: Tetracarbonylcobaltio-chloro-stannanes; Tin; Cobalt; Carbonyl; X -Ray Structure

About the article

Received: 1990-07-16

Published Online: 2014-06-02

Published in Print: 1991-02-01


Citation Information: Zeitschrift für Naturforschung B, Volume 46, Issue 2, Pages 187–191, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1991-0211.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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