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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2016: 0.631

CiteScore 2017: 0.68

SCImago Journal Rank (SJR) 2017: 0.277
Source Normalized Impact per Paper (SNIP) 2017: 0.394

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1865-7117
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Volume 46, Issue 6

Issues

Metallkomplexe in Anorganischen Matrices, 5 [1] / Metal Complexes in Inorganic Matrices, 5 [1]

Katalytische Silanoxidation an einem heterogenisierten Rhodium-Komplex /Catalytic Silane Oxidation at a Heterogenized Rhodium Complex

Christian Egger / Ulrich Schubert
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1991-0614

A heterogenized rhodium complex, prepared by sol-gel processing of Rh(CO)Cl[PPh2CH2CH2Si(OEt)3]2 and Si(OEt)4, is shown to catalyze the conversion of the silanes H4-nSiPh„ (n = 1 - 3) or (HMe2Si)2O to (poly)siloxanes by air or water. Using THF as a solvent, the silanoles Ph3SiOH or Ph2Si(OH)2 are obtained instead. The reaction of phenylacetic acid or acetic acid with HSiPh3 to give silyl esters is catalyzed by the same compound.

About the article

Received: 1991-01-14

Published Online: 2014-06-02

Published in Print: 1991-06-01


Citation Information: Zeitschrift für Naturforschung B, Volume 46, Issue 6, Pages 783–788, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1991-0614.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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[1]
Bhanu P. S. Chauhan, Alok Sarkar, Moni Chauhan, and Abhishek Roka
Applied Organometallic Chemistry, 2009, Volume 23, Number 10, Page 385
[2]
Stanislav K. Ignatov, Nicholas H. Rees, Alexei A. Merkoulov, Stuart R. Dubberley, Alexei G. Razuvaev, Philip Mountford, and Georgii I. Nikonov
Chemistry - A European Journal, 2008, Volume 14, Number 1, Page 296

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