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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2017: 0.757

CiteScore 2017: 0.68

SCImago Journal Rank (SJR) 2017: 0.277
Source Normalized Impact per Paper (SNIP) 2017: 0.394

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ISSN
1865-7117
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Volume 46, Issue 9

Issues

35Cl NQR and X-Ray Studies of Hexachloropalladates A2PdCl6 (A = Rb, Cs, NH4) and the Cl2 – Clathrates Bis(tetramethylammonium)hexachloropalladate (Me4N)2PdCl6 · Cl2 and Bis(tetramethylammonium)hexachlorostannate (Me4N)2SnCl6 · Cl2

Peter Storck
  • Institut für physikalische Chemie, Physikalische Chemie III, Technische Hochschule Darmstadt, Petersenstraße 20, D-6100 Darmstadt, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Alarich Weiss
  • Institut für physikalische Chemie, Physikalische Chemie III, Technische Hochschule Darmstadt, Petersenstraße 20, D-6100 Darmstadt, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1991-0913

The 35Cl NQR frequencies of A2PdCl6 were studied. For A = (CH3)4N+ a clathrate [(CH3)4N]2PdCl6 · Cl2 was found and its crystal structure was determined (Fd3 c, Z = 32, a = 2554.5 pm, R = 0.062). The clathrate [(CH3)4N]2SnCl6 · Cl2 was prepared, too. It is isomorphous with the corresponding palladium salt. The results of the 35Cl NQR studies are discussed on the basis of the crystal structure.

About the article

Received: 1990-12-29

Published Online: 2014-06-02

Published in Print: 1991-09-01


Citation Information: Zeitschrift für Naturforschung B, Volume 46, Issue 9, Pages 1214–1218, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1991-0913.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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