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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences


IMPACT FACTOR 2017: 0.757

CiteScore 2017: 0.68

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Source Normalized Impact per Paper (SNIP) 2017: 0.394

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1865-7117
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Volume 49, Issue 12

Issues

Lanthanoiden-Komplexe, IX [1]. Reaktivitätsbestimmender Einfluß der Ligandenkonstitution bei Seltenerdamiden: Herstellung und Struktur sterisch überladener Alkoxid-Komplexe / Lanthanoid Complexes, IX [1]. Reactivity Control of Lanthanoid Amides through Ligand Effects: Synthesis and Structures of Sterically Congested Alkoxy Complexes

Wolfgang A. Herrmann
  • Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstraße 4, D-85747 Garching b. München
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/ Reiner Anwander
  • Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstraße 4, D-85747 Garching b. München
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/ Florian C. Munck
  • Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstraße 4, D-85747 Garching b. München
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/ Wolfgang Scherer
  • Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstraße 4, D-85747 Garching b. München
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/ Veronique Dufaud
  • Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstraße 4, D-85747 Garching b. München
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/ Norbert W. Huber
  • Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstraße 4, D-85747 Garching b. München
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/ Georg R. J. Artus
  • Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstraße 4, D-85747 Garching b. München
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Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1994-1225

It is shown that the introduction of sterically demanding ligands in lanthanoid metal complexes can depend more on the precise composition of the lanthanoid precursor than on the size of the new ligand. Thus, tris(r-butyl)methanol (“rmojt-H”) does not react with the amides Ln[N(SiMe3)2]3 of the “late” (small) lanthanoid metals. However, fast and clean reactions occur with the sterically less demanding derivatives Ln[N(SiHMe2)2]3, with new homoleptic complexes Ln(tritox)3 (Ln = Y, Nd) being formed with practically all metals of this group of elements. The molecular and crystal structures of some lanthanoid amides and alkoxides are described.

: Lanthanoid Complexes; Alkoxides; Amides; Synthesis; Structure

About the article

Received: 1994-03-30

Published Online: 2014-06-02

Published in Print: 1994-12-01


Citation Information: Zeitschrift für Naturforschung B, Volume 49, Issue 12, Pages 1789–1797, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1994-1225.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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