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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Neue Synthesen für homonukleare Cobalthydrid-Clusterverbindungen / New Synthetic Routes to Homonuclear Cobalt Hydride Clusters

  • Jörg J. Schneider

Several homonuclear cobalt hydride clusters are accessible by reacting the complexes (η5-CpR)Co(η2-ethene)2 (R = H5, Me5) 3, 4 with (C2H5)2AlH followed by alcoholysis of the crude reaction mixtures. Depending on the degree of alkyl substitution, different nuclearities of the resulting clusters have been observed. In the case of the pentamethyl substituted derivative (η5-Cp*)Co(η2-ethene) 4 a mixture of di-, tri- and tetranuclear cobalt hydride clusters namely [(η5-Cp*)Co]2H3 1, [(η5-Cp*)Co]3H4 2 and [(η5-Cp*)Co]4H4 7 were form­ed and separated by repeated crystallization. When reacting the parent compound (η5-Cp)Co(η2-ethene) 3 with (C2H5)2AlH and quenching the reaction mixture with alcohol at low temperature, the tetranuclear cobalt cluster [(η5-Cp)Co]4H4 5 is the main product. Aside from this, trace amounts of the cobalt alkylidine cluster [(η5-Cp)Co]4μ-[C(CH3)]H 6 were formed as detected by mass spectrometry. For the first time a direct synthesis of [(η5-Cp**)Co]3H4 10 and [(η5-Cp**)Co]4H4 11 was achieved by reaction of cobalt atoms with tetramethyl-ethyl-1,3-cyclopentadiene (mixture of isomers) in methylcyclohexane at -120 °C. However, the main product of this metal atom reaction is the mononuclear cobalt sandwich compound (η5-Cp**)Co(η4-tetramethyl-ethyl-1,3-cyclopentadiene) 9 as a mixture of isomers. The trinuclear cobalt alkylidine cluster [(η5-Cp*)Co]3μ3-[C(CH3)]2 8 is formed when reacting (η5-CpR)Co(η2-ethene)2 3 with equimolar amounts of di-isobutyl-aluminium- hydride or the borabicyclus 9-BBN.

Received: 1993-12-3
Published Online: 2014-6-2
Published in Print: 1994-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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