Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2016: 0.631

SCImago Journal Rank (SJR) 2016: 0.237
Source Normalized Impact per Paper (SNIP) 2016: 0.332

Online
ISSN
1865-7117
See all formats and pricing
More options …
Volume 50, Issue 12

Issues

Zur Synthese und Kristallstruktur von Kupferzinkpyroboratoxid Cu2Zn(B2O5)O / Synthesis and Crystal Structure of Copper Zinc Pyroborate Oxide Cu2Zn(B2O5)O

Silke Busche
  • Institut für Anorganische Chemie der Christian-Albrechts-Universität zu Kiel, Otto-Hahn-Platz 6 - 7 , D-24098 Kiel
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Karsten Bluhm
  • Institut für Anorganische Chemie der Christian-Albrechts-Universität zu Kiel, Otto-Hahn-Platz 6 - 7 , D-24098 Kiel
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1995-1212

The compound Cu2Zn(B2O5)O was prepared by using a B2O3 flux technique, and single crystals were investigated by X-ray diffraction (monoclinic symmetry, space group C52h-P21/c ). The structure is isotypic to Cu2Co(B2O5)O with lattice parameters a = 327.38(2), b = 1479.4(3), c = 915.39(13), β = 95.794(11)°, Z = 4, but with the significant difference that zinc is pentacoordinated by oxygen. Copper exhibits a nearly square planar or a square pyramidal coordination, respectively. The structure contains isolated B2O5 units and oxygen which is not coordinated to boron.

Keywords: Copper; Zinc; Pyroborate; Oxide; Crystal Structure

About the article

Received: 1995-05-17

Published Online: 2014-06-02

Published in Print: 1995-12-01


Citation Information: Zeitschrift für Naturforschung B, Volume 50, Issue 12, Pages 1854–1858, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1995-1212.

Export Citation

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

Comments (0)

Please log in or register to comment.
Log in