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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year

IMPACT FACTOR 2017: 0.757

CiteScore 2017: 0.68

SCImago Journal Rank (SJR) 2017: 0.277
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Volume 50, Issue 6


Synthese und Molekülstrukturen der Molybdän(II)-Komplexe MoCl2(PMe3)2 und [Mo(μ-PPh2)(PPh2)(PMe3)]2 / Synthesis and Molecular Structures of the Molybdenum(II) Complexes MoCl2(PMe3)2 and [Mo(μ-PPh2)(PPh2)(PMe3)]2

Katharina Fromm / Monika Plaikner / Evamarie Hey-Hawkins
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1995-0610

Li2P(2,4,6-Me3C6H2) reacts with Cp°MoCl2(PMe3)2 (Cp° = C5Me4Et) with reductive cleavage of the Mo -Cp° bond to yield MoCl2(PMe3)2 (1). The reaction of the Mo(II) derivative MoCl2(PMe3)4 with two equivalents of KPPh2(dioxane)2 yields [Mo(μ-PPh2)(PPh2)(PMe3)]2 (2). Both have been characterized by X-ray crystal structure determination.

Keywords : Molybdenum (II) Complexes; Diphenylphosphido Ligands

About the article

Received: 1994-10-28

Published Online: 2014-06-02

Published in Print: 1995-06-01

Citation Information: Zeitschrift für Naturforschung B, Volume 50, Issue 6, Pages 894–898, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1995-0610.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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