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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2016: 0.631

SCImago Journal Rank (SJR) 2016: 0.237
Source Normalized Impact per Paper (SNIP) 2016: 0.332

Online
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1865-7117
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Volume 51, Issue 12 (Dec 1996)

Issues

Untersuchungen zur Säurestärke von Alkanpolysulfonsäuren / Investigations on the Acid-Strength of Alkanepolysulfonic Acids

Ralf Jüschke
  • Fachbereich 6 Anorganische Chemie der Gerhard-Mercator-Universität, GH Duisburg, D-47048 Duisburg
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Peter Sartori
  • Fachbereich 6 Anorganische Chemie der Gerhard-Mercator-Universität, GH Duisburg, D-47048 Duisburg
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1996-1205

The acid strength of alkanepolysulfonic acids was measured using the correlation between the 29Si NMR shift of the corresponding trimethylsilylester of an acid and the pKS1-value of the acid. Alkanepolysulfonic trimethylsilylesters XHC(SO3-SiMe3)2, X2C(SO3-SiMe3)2, XC(SO3- SiMe3)3 and Me3Si-O3S-(CR2)n-SO3-SiMe3 with X = H, F, Cl, Br, I and R = H, F and n = 1 - 5 were investigated.

: Alkanesulfonic Acids; Acidity; 29Si NMR Spectra

About the article

Received: 1996-08-15

Published Online: 2014-06-02

Published in Print: 1996-12-01


Citation Information: Zeitschrift für Naturforschung B, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1996-1205.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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