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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year

IMPACT FACTOR 2017: 0.757

CiteScore 2017: 0.68

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Volume 54, Issue 12


(CH3NH3)2Sb2S4, a New Thioantimonate(III) with Building Groups Stabilized by Hydrogen Bonds

Michael Schur / Astrid Gruhl / Christian Näther / Inke Jeß / Wolfgang Bensch
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1999-1208

(CH3NH3)2Sb2S4 has been isolated from the reaction of antimony with sulfur in the presence of manganese in an ethanolic solution of methylamine under solvothermal conditions. Two pyramidal SbS3 units are linked via common S-S edges to give dimeric Sb2S42- anions, which are joined via secondary Sb···S contacts of 3.074(2) and 2.975(2) Å forming infinite 1 [SbS2]-2n chains consisting of edge-linked ψ-SbS4 trigonal bipyramids. The cis configuration of the Sb2S42- anions in the title compound is observed for the first time. A specific hydrogenbonding pattern between the amino-hydrogen and the sulfur atoms stabilizes this configuration and gives rise to anionic layers separated by the methyl groups.

Keywords : Thioantimonates; Solvothermal Synthesis; Crystal Structure; Hydrogen Bonding; Polymeric Anions

About the article

Received: 1999-07-21

Published Online: 2014-06-02

Published in Print: 1999-12-01

Citation Information: Zeitschrift für Naturforschung B, Volume 54, Issue 12, Pages 1524–1528, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1999-1208.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung.

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