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Licensed Unlicensed Requires Authentication Published by De Gruyter June 2, 2014

Hydrolytische Bildung von Perchlorsiloxanen / Formation of Chlorosiloxanes by Hydrolysis

  • Heike Quellhorst , Andreas Wilkening , Nicola Söger and Michael Binnewies

During the reaction of Si2OCl6 with H2O in the gas phase the intermediate Si2OCl5OH has been observed by mass-spectrometry. Reactive intermediates like this are responsible for the formation of higher chlorosilanes by slow hydrolysis reactions of chlorosilanes and -siloxanes. Reaction products of inter- and intramolecular condensation reactions have been observed by GC-MS-methods.

Received: 1999-2-18
Published Online: 2014-6-2
Published in Print: 1999-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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