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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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Volume 56, Issue 6


Fluoreliminierung aus Graphitfluorid mit Magnesium / Defluorination of Graphite Fluoride Applying Magnesium Emst-Christian Koch

Emst-Christian Koch
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-2001-0606


Consolidated stoichiometric mixtures of graphite fluoride (1) and magnesium (2) upon igni­ tion under argon atmosphere (0,1 MPa) yield very high flame temperature of ~ 5600 K as determined by infrared emission spectroscopy. The combustion product was analysed by X-ray powder diffraction and revealed the presence of magnesium fluoride and graphite as well as structurally low ordered carbon. A possible reaction mechanism is discussed.

Keywords : Graphite Fluoride; Defluorination; Magnesium

About the article

Received: 2001-03-05

Published Online: 2014-06-02

Published in Print: 2001-06-01

Citation Information: Zeitschrift für Naturforschung B, Volume 56, Issue 6, Pages 512–516, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2001-0606.

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