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Licensed Unlicensed Requires Authentication Published by De Gruyter June 2, 2014

Synthesis and Structure of trans-Dichloro-tetra(pyrazole)-gallium(III) Chloride and Tetrachlorogallate(III)

  • Stefan Nogai , Annette Schier and Hubert Schmidbaur EMAIL logo

[GaCl2(pyrazole)4]+Cl- and [GaCl2(pyrazole)4]+GaCl4- are formed in the reaction of pyrazole and anhydrous gallium trichloride in toluene/diethyl ether. The crystal structure of the chloride salt shows cations in a trans-conufiguration which are associated with the chloride counterions through N-H- -Cl hydrogen bonds.

Received: 2001-11-15
Published Online: 2014-6-2
Published in Print: 2002-2-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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