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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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1865-7117
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Volume 63, Issue 9

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First Trichloroaluminum Adducts of Silyliminoborenes

Holger Ott
  • Institut für Anorganische Chemie der Georg-August-Universität Göttingen, Tammannstraße 4, 37077 Göttingen, Germany
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/ Christoph Matthes
  • Institut für Anorganische Chemie der Georg-August-Universität Göttingen, Tammannstraße 4, 37077 Göttingen, Germany
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/ Stefan Schmatz
  • Institut für Physikalische Chemie der Georg-August-Universität Göttingen, Tammannstraße 6, 37077 Göttingen, Germany
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/ Uwe Klingebiel
  • Institut für Anorganische Chemie der Georg-August-Universität Göttingen, Tammannstraße 4, 37077 Göttingen, Germany
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/ Dietmar Stalke
  • Institut für Anorganische Chemie der Georg-August-Universität Göttingen, Tammannstraße 4, 37077 Göttingen, Germany
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Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-2008-0901

The reactions between the fluoroboranes [(Me3Si)2N]2BF or (Me3Si)2N-BF-N(CMe3)SiMe3 and AlCl3 in diethyl ether afforded the first tri- and disilylated aminoiminoborenes, which were isolated and structurally confirmed as AlCl3 adducts, Me3Si(AlCl3)N=B=N(R)SiMe3, [R = SiMe3 (1), CMe3 (2)]. Density functional theory calculations of 1 and 2 were performed to understand the regioselectivity of the adduct formation.

Keywords: Aminoiminoborene; Silyliminoborene; Aluminum Halide Adducts; Crystal Structure; Density Functional Theory

About the article

Received: 2008-05-29

Published Online: 2014-06-02

Published in Print: 2008-09-01


Citation Information: Zeitschrift für Naturforschung B, Volume 63, Issue 9, Pages 1023–1026, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2008-0901.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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