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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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1865-7117
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Volume 64, Issue 5

Issues

A New Type of 1-D Thioindates, [M(en)3]0.5[InS2] (M = Co, Ni), Synthesized by Solvothermal Reaction

Jian Zhou
  • Department of Chemistry and Key Laboratory of Organic Synthesis of Jiangsu Province, Soochow University, Suzhou 215123, P.R. China
  • Department of Chemistry and Biology, Yulin Normal University, Yulin 537000, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Yong Zhang
  • Department of Chemistry and Key Laboratory of Organic Synthesis of Jiangsu Province, Soochow University, Suzhou 215123, P.R. China
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  • De Gruyter OnlineGoogle Scholar
/ Ming-Hui Zhang
  • Department of Chemistry and Key Laboratory of Organic Synthesis of Jiangsu Province, Soochow University, Suzhou 215123, P.R. China
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/ Zhi-Xin Lei
  • Department of Chemistry and Key Laboratory of Organic Synthesis of Jiangsu Province, Soochow University, Suzhou 215123, P.R. China
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/ Jie Dai
  • Corresponding author
  • Department of Chemistry and Key Laboratory of Organic Synthesis of Jiangsu Province, Soochow University, Suzhou 215123, P.R. China
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Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-2009-0505

Two thioindates [M(en)3]0.5InS2 [en = ethylenediamine; M = Ni (1), Co (2)] were prepared by the reaction of In2S3, Ni (or Co) and S under solvothermal conditions, and their crystal structures have been determined. Both compounds are isostructural and crystallize in the orthorhombic space group Cmcm. The crystal structures consist of a new type of 1-D sinusoidal chain, which complements the reported I - III types of 1-D [InQ2]n (Q = S, Te) anions built from InQ4 tetrahedra. The band gaps of 3.47 eV for I and 3.31 eV for 2 have been derived from optical absorption spectra.

Graphical Abstract

A New Type of 1-D Thioindates, [M(en)3]0.5[InS2] (M = Co, Ni), Synthesized by Solvothermal Reaction

A New Type of 1-D Thioindates, [M(en)3]0.5[InS2] (M = Co, Ni), Synthesized by Solvothermal Reaction

Keywords : Solvothermal Synthesis; Crystal Structure; Thioindate; One-dimensional

About the article

Received: 2009-12-24

Published Online: 2014-06-02

Published in Print: 2009-05-01


Citation Information: Zeitschrift für Naturforschung B, Volume 64, Issue 5, Pages 504–508, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2009-0505.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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