Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Zeitschrift für Naturforschung B

A Journal of Chemical Sciences


IMPACT FACTOR 2018: 0.961

CiteScore 2018: 0.91

SCImago Journal Rank (SJR) 2018: 0.263
Source Normalized Impact per Paper (SNIP) 2018: 0.505

Online
ISSN
1865-7117
See all formats and pricing
More options …
Volume 65, Issue 3

Issues

Syntheses and Palladium, Platinum, and Borane Adducts of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH2)mCH=CH2)3

Agnieszka J. Nawara-Hultzsch
  • Institut für Organische Chemie and Interdisciplinary Center for Molecular Materials, Friedrich-Alexander-Universität Erlangen-Nürnberg, Henkestraße 42, 91054 Erlangen, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Katrin Skopek
  • Institut für Organische Chemie and Interdisciplinary Center for Molecular Materials, Friedrich-Alexander-Universität Erlangen-Nürnberg, Henkestraße 42, 91054 Erlangen, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Takanori Shima
  • Institut für Organische Chemie and Interdisciplinary Center for Molecular Materials, Friedrich-Alexander-Universität Erlangen-Nürnberg, Henkestraße 42, 91054 Erlangen, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Michał Barbasiewicz
  • Institut für Organische Chemie and Interdisciplinary Center for Molecular Materials, Friedrich-Alexander-Universität Erlangen-Nürnberg, Henkestraße 42, 91054 Erlangen, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Gisela D Hess
  • Institut für Organische Chemie and Interdisciplinary Center for Molecular Materials, Friedrich-Alexander-Universität Erlangen-Nürnberg, Henkestraße 42, 91054 Erlangen, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Dirk Skaper
  • Institut für Organische Chemie and Interdisciplinary Center for Molecular Materials, Friedrich-Alexander-Universität Erlangen-Nürnberg, Henkestraße 42, 91054 Erlangen, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ John A Gladysz
  • Corresponding author
  • Institut für Organische Chemie and Interdisciplinary Center for Molecular Materials, Friedrich-Alexander-Universität Erlangen-Nürnberg, Henkestraße 42, 91054 Erlangen, Germany
  • Department of Chemistry, Texas A&M University, PO Box 30012, College Station, Texas 77842-3012, USA
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-2010-0327

Reactions of Br(CH2)mCH=CH2 with Mg powder and then PCl3 (0.33 equiv.) afford P((CH2)m- CH=CH2)3 (1; m = a, 4; b, 5; c, 6; d, 7; e, 8; f, 9; 52 - 87%). Reactions of 1a - c, e with PdX2(COD) (X = Cl, Br) give trans-PdX2(P((CH2)mCH=CH2)3)2 (35 - 92%). Reactions of 1b - e with PtCl2 in benzene give mainly trans-PtCl2(P((CH2)mCH=CH2)3)2 (trans-5b-e; 52 - 75%), whereas those with K2PtCl4 in water give mainly cis-5b-e (33 - 70%). The reaction of equimolar quantities of 1c and H3B・S(CH3)2 gives the 1 : 1 adduct H3B・P((CH2)6CH=CH2)3 (85%). In none of these transformations are by-products derived from the C=C linkages observed

Graphical Abstract

Syntheses and Palladium, Platinum, and Borane Adducts of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH2)mCH=CH2)3

Syntheses and Palladium, Platinum, and Borane Adducts of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH2)mCH=CH2)3

Keywords : Phosphine; Phosphine Borane; Palladium; Platinum; α,ω-Diene

About the article

Received: 2009-12-07

Published Online: 2014-06-02

Published in Print: 2010-03-01


Citation Information: Zeitschrift für Naturforschung B, Volume 65, Issue 3, Pages 414–424, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2010-0327.

Export Citation

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

[1]
Abigail H. Shelton, Silvano R. Valandro, Randi S. Price, Galyna G. Dubinina, Khalil A. Abboud, Geoffrey Wicks, Aleksander Rebane, Muhammad Younus, and Kirk S. Schanze
The Journal of Physical Chemistry A, 2019
[2]
Tobias Fiedler, Michał Barbasiewicz, Michael Stollenz, and John A Gladysz
Beilstein Journal of Organic Chemistry, 2018, Volume 14, Page 2354
[3]
J. Guenther, J. Reibenspies, and J. Blümel
Advanced Synthesis & Catalysis, 2011, Volume 353, Number 2-3, Page 443
[4]
Michael Stollenz, Hemant Joshi, Andreas Ehnbom, Tobias Fiedler, Sugam Kharel, Joseph H. Reibenspies, Nattamai Bhuvanesh, Michael B. Hall, and John A. Gladysz
Polyhedron, 2018
[7]
[8]
Esther Steigleder, Takanori Shima, Georgette M. Lang, Andreas Ehnbom, Frank Hampel, and John A. Gladysz
Organometallics, 2017, Volume 36, Number 15, Page 2891
[10]
Georgette M. Lang, Nattamai Bhuvanesh, Joseph H. Reibenspies, and John A. Gladysz
Organometallics, 2016, Volume 35, Number 17, Page 2873
[11]
Tobias Fiedler, Nattamai Bhuvanesh, Frank Hampel, Joseph H. Reibenspies, and John A. Gladysz
Dalton Trans., 2016, Volume 45, Number 16, Page 7131
[12]
Georgette M. Lang, Dirk Skaper, Takanori Shima, Michael Otto, Leyong Wang, and John A. Gladysz
Australian Journal of Chemistry, 2015, Volume 68, Number 9, Page 1342
[13]
Michael Stollenz, Michał Barbasiewicz, Agnieszka J. Nawara-Hultzsch, Tobias Fiedler, Ryan M. Laddusaw, Nattamai Bhuvanesh, and John A. Gladysz
Angewandte Chemie International Edition, 2011, Volume 50, Number 29, Page 6647
[14]
Agnieszka J. Nawara-Hultzsch, Michael Stollenz, Michał Barbasiewicz, Sławomir Szafert, Tadeusz Lis, Frank Hampel, Nattamai Bhuvanesh, and John A. Gladysz
Chemistry - A European Journal, 2014, Volume 20, Number 16, Page 4617

Comments (0)

Please log in or register to comment.
Log in