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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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1865-7117
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Volume 66, Issue 3 (Mar 2011)

Issues

{[(PhCH2Sn)123-O)14(μ-OH)6](F3CSO3)2}: A New Dodecanuclear Organostannoxane

Laurent Plasseraud
  • Institut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB), UMR CNRS 5260, UFR Sciences et Techniques, 9 allée A. Savary, BP 47870, 21078 DIJON Cedex, France
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/ Hélène Cattey
  • Institut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB), UMR CNRS 5260, UFR Sciences et Techniques, 9 allée A. Savary, BP 47870, 21078 DIJON Cedex, France
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  • De Gruyter OnlineGoogle Scholar
/ Philippe Richard
  • Institut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB), UMR CNRS 5260, UFR Sciences et Techniques, 9 allée A. Savary, BP 47870, 21078 DIJON Cedex, France
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Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-2011-0307

The new dodecanuclear organostannoxane {[(PhCH2Sn)123-O)14(μ-OH)6](F3CSO3)2} (2) has been isolated as single crystals from the reaction of trifluoromethanesulfonic acid (F3CSO3H) with the decanuclear dibenzyltin(IV)-oxo cluster, [(PhCH2)2SnO]6{[(PhCH2)2SnOH]2(CO3)}2 (1), in [D3]acetonitrile, at room temperature. Compound 2 was structurally characterized by X-ray diffraction analysis, multinuclear NMR and IR spectroscopy, mass spectrometry, and thermogravimetry. The structure of 2 can be described as a football cage framework containing twelve tin atoms, exhibiting two distinct coordination geometries, penta- and hexacoordinated respectively, and linked together through μ3-O and μ-OH ligands. Resulting from Sn-C bond cleavage, all tin atoms are only connected to one benzyl ligand. Furthermore, two of the three oxygen atoms of each trifluoromethanesulfonate counteranions are involved in hydrogen bonding interactions with bridging μ-OH groups of two distinct Sn12 cations leading to the propagation of a two-dimensional polymeric network.

Graphical Abstract

{[(PhCH2Sn)12(μ3-O)14(μ-OH)6](F3CSO3)2}: A New Dodecanuclear Organostannoxane

{[(PhCH2Sn)123-O)14(μ-OH)6](F3CSO3)2}: A New Dodecanuclear Organostannoxane

Keywords: Polyhydroxyorganotin(IV) Cluster; Sn-O-Sn Framework; Triflate; Cleavage Reactions; Crystal Structure

About the article

Received: 2010-11-16

Published Online: 2014-06-02

Published in Print: 2011-03-01


Citation Information: Zeitschrift für Naturforschung B, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2011-0307.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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