Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Zeitschrift für Naturforschung B

A Journal of Chemical Sciences


IMPACT FACTOR 2017: 0.757

CiteScore 2017: 0.68

SCImago Journal Rank (SJR) 2017: 0.277
Source Normalized Impact per Paper (SNIP) 2017: 0.394

Online
ISSN
1865-7117
See all formats and pricing
More options …
Volume 68, Issue 5-6

Issues

Structures of Energetic Acetylene Derivatives HC≡CCH2ONO2, (NO2)3CCH2C≡CCH2C(NO2)3 and Trinitroethane, (NO2)3CCH3

Thomas M. Klapötke
  • Department of Chemistry, Ludwig-Maximilian University of Munich, Butenandtstraße 5 – 13 (D), 81377 Munich, Germany
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Burkhard Krumm
  • Department of Chemistry, Ludwig-Maximilian University of Munich, Butenandtstraße 5 – 13 (D), 81377 Munich, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Richard Moll
  • Department of Chemistry, Ludwig-Maximilian University of Munich, Butenandtstraße 5 – 13 (D), 81377 Munich, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Alexander Penger
  • Department of Chemistry, Ludwig-Maximilian University of Munich, Butenandtstraße 5 – 13 (D), 81377 Munich, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Stefan M. Sproll
  • Department of Chemistry, Ludwig-Maximilian University of Munich, Butenandtstraße 5 – 13 (D), 81377 Munich, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Raphael J. F. Berger
  • Inorganic and Structural Chemistry, Bielefeld University, Universitätsstraße 25, 33615 Bielefeld, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Stuart A. Hayes
  • Inorganic and Structural Chemistry, Bielefeld University, Universitätsstraße 25, 33615 Bielefeld, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Norbert W. Mitzel
  • Inorganic and Structural Chemistry, Bielefeld University, Universitätsstraße 25, 33615 Bielefeld, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2014-06-02 | DOI: https://doi.org/10.5560/znb.2013-2311

The molecular structures and relative ratios of the two conformers (anti and gauche) of HCCCH2ONO2 detected in the gas phase at room temperature have been determined by electron diffraction. The results are discussed on the basis of quantum chemical calculations. The molecular structures of (NO2)3CCH2C≡CCH2C(NO2)3 and (NO2)3CCH3 have been determined by X-ray diffraction. A109Ag NMR study was performed for silver trinitromethanide Ag[C(NO2)3] in various polar solvents.

Graphical Abstract

Structures of Energetic Acetylene Derivatives HC≡CCH2ONO2, (NO2)3CCH2C≡CCH2C(NO2)3 and Trinitroethane, (NO2)3CCH3

Structures of Energetic Acetylene Derivatives HC≡CCH2ONO2, (NO2)3CCH2C≡CCH2C(NO2)3 and Trinitroethane, (NO2)3CCH3

Keywords: Gas-phase Electron Diffraction; X-Ray Diffraction; High Energy Dense Oxidizer; Trinitromethyl; Silver NMR

About the article

Received: 2012-11-27

Published Online: 2014-06-02

Published in Print: 2013-06-01


Citation Information: Zeitschrift für Naturforschung B, Volume 68, Issue 5-6, Pages 719–731, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.5560/znb.2013-2311.

Export Citation

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung.

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

[1]
Yury V. Vishnevskiy, Denis S. Tikhonov, Jan Schwabedissen, Hans-Georg Stammler, Richard Moll, Burkhard Krumm, Thomas M. Klapötke, and Norbert W. Mitzel
Angewandte Chemie, 2017, Volume 129, Number 32, Page 9748
[2]
Yury V. Vishnevskiy, Denis S. Tikhonov, Jan Schwabedissen, Hans-Georg Stammler, Richard Moll, Burkhard Krumm, Thomas M. Klapötke, and Norbert W. Mitzel
Angewandte Chemie International Edition, 2017, Volume 56, Number 32, Page 9619
[3]
Thomas M. Klapötke, Burkhard Krumm, Richard Moll, Sebastian F. Rest, Yury V. Vishnevskiy, Christian Reuter, Hans-Georg Stammler, and Norbert W. Mitzel
Chemistry - A European Journal, 2014, Volume 20, Number 40, Page 12962

Comments (0)

Please log in or register to comment.
Log in