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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2015: 0.686

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1865-7117
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A Dinuclear Palladium(II) Complex of the {N(SPPh2)2}- Ligand – Synthesis and Structure

Sebastian Marks
  • Institut für Anorganische Chemie, Karlsruher Institut für Technologie, Engesserstr. 15, 76131 Karlsruhe, Germany
/ Peter W. Roesky
  • Institut für Anorganische Chemie, Karlsruher Institut für Technologie, Engesserstr. 15, 76131 Karlsruhe, Germany
  • :
Published Online: 2014-06-02 | DOI: https://doi.org/10.5560/znb.2013-3066

The synthesis and characterization including the crystal structure of the dinuclear palladium( II) complex [(k-S,S’)-{N(SPPh2)2}Pd(m-{k2-S'',S'''})-{N(SPPh2)2}PdCl2] (1) are reported. Compound 1 was obtained from the reaction of [PdCl2(COD)] (COD=1,5-cyclooctadiene) and HN(SPPh2)2 in a 1:1 molar ratio in CH2Cl2. The {N(SPPh2)2}- ligands act both as bridging and/or terminally chelating units

Graphical Abstract

A Dinuclear Palladium(II) Complex of the {N(SPPh2)2}- Ligand – Synthesis and Structure

Keywords: Bimetallic Complex; Palladium; PNP Ligand; S Donor Ligand


Received: 2013-02-22

Published Online: 2014-06-02

Published in Print: 2013-06-01


Citation Information: Zeitschrift für Naturforschung B. Volume 68, Issue 5-6, Pages 557–560, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.5560/znb.2013-3066, June 2014

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