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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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Volume 70, Issue 3

Issues

mer-Triammine trifluorido vanadium(III), mer-[VF3(NH3)3]: synthesis and crystal structure

Patrick Woidy
  • Technische Universität München, Zentrale Technisch-Wissenschaftliche Betriebseinheit Radiochemie München RCM, Walther-Meißner-Straße 3, 85747 Garching, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Florian Kraus
  • Corresponding author
  • Anorganische und Fluorchemie der Philipps-Universität Marburg, Hans-Meerwein-Straße 4, 35032 Marburg, Germany
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2015-03-10 | DOI: https://doi.org/10.1515/znb-2014-0249

Abstract

Vanandium trifluoride reacts with dry liquid ammonia under the formation of lilac plate-shaped crystals of mer-triammine trifluorido vanadium(III) (1), mer-[VF3(NH3)3]. Single-crystal X-ray analysis was carried out at low temperature to elucidate the structure. The compound crystallizes in the monoclinic space group P21/c with a = 5.7284(4), b = 9.2033(5), c = 10.5271(6) Å, β = 91.795(6)°, and V = 554.72(6) Å3 at 123 K with Z = 4. The discrete [VF3(NH3)3] molecules are interconnected by hydrogen bonds.

Keywords: ammine complexes; crystal structures; fluoride; liquid ammonia; vanadium(III)

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About the article

Corresponding author: Florian Kraus, Anorganische und Fluorchemie der Philipps-Universität Marburg, Hans-Meerwein-Straße 4, 35032 Marburg, Germany, e-mail:


Received: 2014-12-08

Accepted: 2015-01-09

Published Online: 2015-03-10

Published in Print: 2015-03-01


Citation Information: Zeitschrift für Naturforschung B, Volume 70, Issue 3, Pages 161–164, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2014-0249.

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