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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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1865-7117
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Volume 70, Issue 4 (Apr 2015)

Issues

Tl2C2O4·H2C2O4: a new crystalline form of thallium(I) oxalate

Oscar E. Piro
  • Departamento de Física and Instituto IFLP (CONICET), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 1900 La Plata, Argentina
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Gustavo A. Echeverría
  • Departamento de Física and Instituto IFLP (CONICET), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 1900 La Plata, Argentina
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Ana C. González-Baró
  • Centro de Química Inorgánica (CEQUINOR, CONICET/UNLP), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, C. Correo 962,1900 La Plata, Argentina
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Enrique J. Baran
  • Corresponding author
  • Centro de Química Inorgánica (CEQUINOR, CONICET/UNLP), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, C. Correo 962,1900 La Plata, Argentina
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  • Other articles by this author:
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Published Online: 2015-03-20 | DOI: https://doi.org/10.1515/znb-2014-0257

Abstract

The title compound was prepared by reaction, in aqueous solution, of Tl2CO3 and H2C2O4·2H2O in a molar ratio of 1:2. Its crystal structure was solved by X-ray diffraction methods. It crystallizes in the monoclinic space group P21/a with Z = 2 molecules per unit cell. The oxalic acid molecule and the oxalate anion are planar, residing on crystallographic inversion centers, and linked to each other by strong O–H···O hydrogen bonds giving rise to a polymeric structure. The Tl(I) ion is in a distorted polyhedral coordination with nine neighboring O atoms, five of oxalate anions and four others of oxalic acid molecules. The FTIR and FT-Raman spectra of the compound were also recorded and are briefly discussed.

Keywords: crystal structure; FTIR spectra; FT-Raman spectra; synthesis; thallium(I) oxalate-oxalic acid

References

  • [1]

    E. J. Baran, P. V. Monje, “Oxalate biominerals” in Metal Ions in Life Sciences, Vol. 4 (Eds.: A. Sigel, H. Sigel, R. K. O. Sigel), J. Wiley, Chichester, 2008, pp. 219.Google Scholar

  • [2]

    P. V. Monje, E. J. Baran, “Plant biomineralization” in Advances in Plant Physiology, Vol. 7 (Ed.: A. Hemantaranjan), Scientific Publishers, Jodhpur, 2004, pp. 395.Google Scholar

  • [3]

    P. V. Monje, E. J. Baran, Plant Physiol. 2002, 128, 707.Google Scholar

  • [4]

    P. V. Monje, E. J. Baran, Phytochemistry 2005, 66, 611.PubMedGoogle Scholar

  • [5]

    P. V. Monje, E. J. Baran, Z. Naturforsch. 2010, 65c, 429.Google Scholar

  • [6]

    E. J. Baran, A. C. González-Baró, M. M. Ciciarelli, C. H. Rolleri, Rev. Biol. Trop. 2010, 58, 1507.PubMedGoogle Scholar

  • [7]

    E. J. Baran, J. Coord. Chem. 2014, 67, 3734.Google Scholar

  • [8]

    D. Y. Naumov, A. V. Virovets, N. V. Podberezkaya, E. V. Boldyreva, Acta Crystallogr. 1995, C51, 60.Google Scholar

  • [9]

    A. N. Christensen, P. Norby, J. C. Hanson, Z. Kristallogr. 1994, 209, 874.Google Scholar

  • [10]

    H. S. Hua, W. R. Ji, T. C. W. Mak, J. Crystallogr. Spectr. Res. 1990, 20, 99.Google Scholar

  • [11]

    P. Orioli, B. Bruni, M. Di Vaira, L. Messori, F. Piccioli, Inorg. Chem. 2002, 41, 4312.Google Scholar

  • [12]

    A. Gleizes, J. Galy, J. Solid State Chem. 1979, 30, 23.Google Scholar

  • [13]

    A. N. Christensen, D. E. Cox, M. S. Lehmann, Acta Chem. Scand. 1989, 43, 19.Google Scholar

  • [14]

    A. Wladimirsky, D. Palacios, M. C. D’Antonio, A. C. González-Baró, E. J. Baran, Spectrochim. Acta 2010, 77A, 334.Google Scholar

  • [15]

    N. Mancilla, M. C. D’Antonio, A. C. González-Baró, E. J. Baran, J. Raman Spectr. 2009, 40, 2050.Google Scholar

  • [16]

    N. Audebrand, S. Raite, D. Louër, Solid State Sci. 2003, 5, 783.Google Scholar

  • [17]

    N. Bulc, L. Golič, Acta Crystallogr. 1983, C39, 174.Google Scholar

  • [18]

    P. Nagy, A. Fischer, J. Glaser, A. Ilyukhin, M. Maliarik, I. Tóth, Inorg. Chem. 2005, 44, 2347.Google Scholar

  • [19]

    T. Ichigo, M. Kimata, Z. Kristallogr. 2006, 221, 762.Google Scholar

  • [20]

    H. F. V. Little, in A Text-Book of Inorganic Chemistry, Vol. IV, Charles Griffin and Co. Ltd, London, 1917, p. 199.Google Scholar

  • [21]

    C. K. Johnson, ortep-II, in A Fortran Thermal-Ellipsoid Plot Program. Report ORNL-5318, Oak Ridge National Laboratory, Oak Ridge, 1976.Google Scholar

  • [22]

    E. D. Stevens, P. Coppens, Acta Crystallogr. 1980, B36, 1864.Google Scholar

  • [23]

    G. A. Jeffrey, G. S. Parry, J. Am. Chem. Soc. 1954, 76, 5283.Google Scholar

  • [24]

    D. A. Reed, M. M. Olmstead, Acta Crystallogr. 1981, B37, 938.Google Scholar

  • [25]

    S. J. Cyvin, I. Alfheim, Acta Chem. Scand. 1970, 24, 2648.Google Scholar

  • [26]

    J. Nieminen, M. Räsänen, J. Murto, J. Phys. Chem. 1992, 96, 5303.Google Scholar

  • [27]

    E. M. S. Maçôas, R. Fausto, M. Pettersson, L. Khriachtchev, M. Räsänen, J. Phys. Chem. A, 2000, 104, 6956.Google Scholar

  • [28]

    V. Mohaček-Grošev, J. Grdadolnik, J. Stare, D. Hadži, J. Raman Spectr. 2009, 40, 1605.Google Scholar

  • [29]

    M. C. D’Antonio, N. Mancilla, A. Wladimirsky, D. Palacios, A. C. González-Baró, E. J. Baran, Vibrat. Spectr. 2010, 53, 218.Google Scholar

  • [30]

    V. M. F. Hammer, E. Libowitzky, G. R. Rossman, Amer. Mineral. 1998, 83, 569.Google Scholar

  • [31]

    E. Libowitzki, Monatsh. Chem. 1999, 130, 1047.Google Scholar

  • [32]

    D. Hadži, Pure Appl. Chem.1965, 11, 435.Google Scholar

  • [33]

    CrysAlisPro, version 1.171.33.48; release 15 September 2009; CrysAlis171.NET, Oxford Diffraction Ltd, Abingdon (2009).Google Scholar

  • [34]

    G. M. Sheldrick, Acta Crystallogr. 2008, A64, 112.Google Scholar

About the article

Corresponding author: Enrique J. Baran, Centro de Química Inorgánica. Facultad de Ciencias Exactas, Universidad Nacional de La Plata, C. Correo 962, 1900 La Plata, Argentina, e-mail:


Received: 2014-11-25

Accepted: 2015-01-09

Published Online: 2015-03-20

Published in Print: 2015-04-01


Citation Information: Zeitschrift für Naturforschung B, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2014-0257.

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