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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences


IMPACT FACTOR 2018: 0.961

CiteScore 2018: 0.91

SCImago Journal Rank (SJR) 2018: 0.263
Source Normalized Impact per Paper (SNIP) 2018: 0.505

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1865-7117
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Volume 71, Issue 1

Issues

Syntheses and crystal structures of two new sodium borates [Na2(H2O)3][B5O8(OH)2] and Na[enH2][B7O10(OH)4]

Yan-Jing Wang
  • Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Ai-Quan Jia
  • Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Xing-Shun Chen
  • Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, P.R. China
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  • De Gruyter OnlineGoogle Scholar
/ Hua-Tian Shi
  • Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, P.R. China
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  • De Gruyter OnlineGoogle Scholar
/ Qian-Feng Zhang
  • Corresponding author
  • Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, P.R. China
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  • Other articles by this author:
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Published Online: 2015-12-11 | DOI: https://doi.org/10.1515/znb-2015-0072

Abstract

Two new sodium borates [Na2(H2O)3][B5O8(OH)2] (1) and Na[enH2][B7O10(OH)4] (2) have been synthesized and their structures have been determined by single-crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic system space group C2/c with a = 11.118(2), b = 16.442(2), c = 13.572(2) Å, β =112.90(1)°, V = 2285.4(5) Å3, and Z = 4. Compound 2 crystallizes in the triclinic space group P1̅, with a = 7.4974(9), b = 8.349(2), c = 11.746(2), α = 93.98(1), β = 97.25(1), γ = 101.18(1)°, V = 712.2(2) Å3, and Z = 2. Compound 1 possesses {Na2B5O8(OH)2·3H2O}n chains which form through the connection of the fundamental building blocks (FBBs) [B5O8(OH)2]2– by sharing Na+ ions, while compound 2 has infinite {Na[B7O10(OH)4]}n sheets which form via the connection of the FBBs [B7O10(OH)4]3– by common Na+ ions.

Keywords: FBBs; single crystal structure; sodium borate; solvothermal

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About the article

Corresponding author: Qian-Feng Zhang, Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, P.R. China, Fax: +86-555-2311059, E-mail:


Received: 2015-04-16

Accepted: 2015-06-17

Published Online: 2015-12-11

Published in Print: 2016-01-01


Citation Information: Zeitschrift für Naturforschung B, Volume 71, Issue 1, Pages 15–21, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2015-0072.

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