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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences


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1865-7117
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Volume 71, Issue 1

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1,3,5-Tris[(trimethylstannyl)ethynyl]- 1,3,5-trimethyl-1,3,5-trisilacyclohexane

Eugen Weisheim
  • Lehrstuhl für Anorganische Chemie und Strukturchemie, Centrum für Molekulare Materialien CM2, Fakultät für Chemie, Universität Bielefeld, Universitätsstraße 25, 33615 Bielefeld, Germany
  • Other articles by this author:
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/ Hans-Georg Stammler
  • Lehrstuhl für Anorganische Chemie und Strukturchemie, Centrum für Molekulare Materialien CM2, Fakultät für Chemie, Universität Bielefeld, Universitätsstraße 25, 33615 Bielefeld, Germany
  • Other articles by this author:
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/ Norbert W. Mitzel
  • Corresponding author
  • Lehrstuhl für Anorganische Chemie und Strukturchemie, Centrum für Molekulare Materialien CM2, Fakultät für Chemie, Universität Bielefeld, Universitätsstraße 25, 33615 Bielefeld, Germany
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Published Online: 2015-12-09 | DOI: https://doi.org/10.1515/znb-2015-0148

Abstract

The reaction of 1,3,5-triethynyl-1,3,5-trimethyl- 1,3,5-trisilacyclohexane with (dimethylamino)trimethylstannane afforded 1,3,5-tris[(trimethylstannyl)ethynyl]- 1,3,5-trimethyl-1,3,5-trisilacyclohexane with tin-functionalised ethynyl groups. The compound was characterized by single-crystal X-ray diffraction, elemental analysis, mass spectrometry, NMR and FT-IR spectroscopy.

Keywords: deprotonation; ethynyl groups; organometallic chemistry; tin; 1,3,5-trisilacyclohexane

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About the article

Corresponding author: Norbert W. Mitzel, Lehrstuhl für Anorganische Chemie und Strukturchemie, Centrum für Molekulare Materialien CM2, Fakultät für Chemie, Universität Bielefeld, Universitätsstraße 25, 33615 Bielefeld, Germany, Fax: (+49) 521 106 6026, E-mail:


Received: 2015-09-22

Accepted: 2015-10-20

Published Online: 2015-12-09

Published in Print: 2016-01-01


Citation Information: Zeitschrift für Naturforschung B, Volume 71, Issue 1, Pages 81–84, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2015-0148.

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