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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences


IMPACT FACTOR 2018: 0.961

CiteScore 2018: 0.91

SCImago Journal Rank (SJR) 2018: 0.263
Source Normalized Impact per Paper (SNIP) 2018: 0.505

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1865-7117
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Volume 71, Issue 11

Issues

Syntheses and crystal structures of two new silver–organic frameworks based on N-pyrazinesulfonyl-glycine: weak Ag···O/N interaction affecting the coordination geometry

Jia-Ming Li
  • Corresponding author
  • Guangxi Colleges and Universities Key Laboratory of Beibu Gulf Oil and Natural Gas Resource Effective Utilization, College of Petroleum and Chemical Engineering, Qinzhou University, Qinzhou 535011, P.R. China
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Kun-Huan He
  • Guangxi Colleges and Universities Key Laboratory of Beibu Gulf Oil and Natural Gas Resource Effective Utilization, College of Petroleum and Chemical Engineering, Qinzhou University, Qinzhou 535011, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Zhong-Feng Shi
  • Guangxi Colleges and Universities Key Laboratory of Beibu Gulf Oil and Natural Gas Resource Effective Utilization, College of Petroleum and Chemical Engineering, Qinzhou University, Qinzhou 535011, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Hui-Yuan Gao
  • School of Chemistry and Pharmacy, Guangxi Normal University, Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education), Guilin 541004, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Yi-Min Jiang
  • Corresponding author
  • School of Chemistry and Pharmacy, Guangxi Normal University, Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education), Guilin 541004, P.R. China
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  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2016-08-17 | DOI: https://doi.org/10.1515/znb-2016-0134

Abstract

Two new metal–organic frameworks, namely, [Ag2(L)]n (1) and {[Ag2.5(L)(bpy)2]·(NO3)0.5·(H2O)4.5}n (2), where H2L=N-pyrazinesulfonyl-glycine and bpy=4,4′-bipyridine, have been synthesized and characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental analysis. X-ray diffraction crystallographic analyses indicate that 1 displays a silver carboxylate-sulfonamide layer structure containing an uncommon heptanuclear [Ag7] cluster wherein four silver(I) atoms form an Ag4 plane with in a three-connected (6, 3) net. The molecular structure of 2 has three crystallographically independent two-coordinate Ag centers with an intersecting Ag-bpy chain structure in a six-connected (3, 6) or a four-connected (4, 4) topology. The L2− ligand serves as a μ7-(η2-O,N), (η2-O′,N′), O,O″,O″′,N,N″ ligand in 1 and as a μ3-(η2-O,N), N,O′ ligand in 2. In the crystal, a 3D supramolecular architecture is formed by coordinative bonding in 1, but through O–H···O bonding as well as π···π stacking in 2. The two compounds show a combination of coordinative bonds, ligand-supported Ag···Ag interactions and weak Ag···O/N coordinative interactions in the solid state.

Keywords: 4,4′-bipyridine; crystal structure; metal–organic frameworks; N-pyrazinesulfonyl-glycine; silver(I) complex

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About the article

Received: 2016-05-25

Accepted: 2016-06-22

Published Online: 2016-08-17

Published in Print: 2016-11-01


Funding Source: Natural Science Foundation of Guangxi Province

Award identifier / Grant number: 2014GXNSFAA118035

Award identifier / Grant number: 2014GXNSFBA118040

Funding Source: National Natural Science Foundation of China

Award identifier / Grant number: 51402158

This work was supported by the Guangxi Provincial Department of Education (Nos. KY2015ZD130, YB2014414) and the Natural Science Foundation of Guangxi Province (Nos. 2014GXNSFAA118035, 2014GXNSFBA118040). The support of the National Natural Science Foundation of China (No. 51402158) is gratefully acknowledged. The authors also acknowledge the financial support by the Opening Project of Guangxi Colleges and Universities Key Laboratory of Beibu Gulf Oil and Natural Gas Resource Effective Utilization (Nos. 2015KLOG09, 2014PY-GJ05).


Citation Information: Zeitschrift für Naturforschung B, Volume 71, Issue 11, Pages 1169–1175, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2016-0134.

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