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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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1865-7117
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Volume 71, Issue 4

Issues

Synthesis, single-crystal structure determination and Raman spectra of the tricyanomelaminates NaA5[C6N9]2 · 4 H2O (A = Rb, Cs)

Olaf Reckeweg
  • Corresponding author
  • Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA
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/ Armin Schulz
  • Max-Planck-Institut für Festkörperforschung, Heisenbergstraße 1, D-70569 Stuttgart, Germany
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  • De Gruyter OnlineGoogle Scholar
/ Francis J. DiSalvo
  • Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA
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Published Online: 2016-03-04 | DOI: https://doi.org/10.1515/znb-2016-0024

Abstract

Transparent colorless crystals of NaA5[C6N9]2 · 4 H2O (A = Rb, Cs) were obtained by blending aqueous solutions of Na3[C6N9] and RbF or CsF, respectively, and subsequent evaporation of the water under ambient conditions. Both compounds crystallize in the space group P21/m (no. 11) with the cell parameters a = 815.56(16), b = 1637.7(4) and c = 1036.4(3) pm, and β = 110.738(12)° for NaRb5[C6N9]2 · 4 H2O and a = 843.32(6), b = 1708.47(11) and c = 1052.42(7) pm, and β = 112.034(2)° for NaCs5[C6N9]2 · 4 H2O, respectively. Raman spectra of the title compounds complement our results.

Keywords: alkali metal; cesium; Raman spectra; rubidium; sodium; tricyanomelaminate

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About the article

Corresponding author: Olaf Reckeweg, Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA, Fax: +1-607-255-4137, E-mail:


Received: 2016-01-15

Accepted: 2016-01-26

Published Online: 2016-03-04

Published in Print: 2016-04-01


Citation Information: Zeitschrift für Naturforschung B, Volume 71, Issue 4, Pages 327–332, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2016-0024.

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