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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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IMPACT FACTOR 2016: 0.631

CiteScore 2017: 0.68

SCImago Journal Rank (SJR) 2017: 0.277
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1865-7117
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Volume 71, Issue 5

Issues

Crystal structures and hydrogenation properties of palladium-rich compounds with elements from groups 12–16

André Götze / Jonas Michael Sander
  • Inorganic Solid State Chemistry, Saarland University, Am Markt, Zeile 3, 66125 Saarbrücken, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Holger Kohlmann
Published Online: 2016-03-24 | DOI: https://doi.org/10.1515/znb-2016-0003

Abstract

We report on crystal structure data and hydrogenation properties of 24 palladium-rich intermetallic compounds with elements from groups 12–16 of the Periodic Table. Refined crystal structures based on X-ray powder diffraction data are presented for Pd3As (Fe3P type structure) and several members of the Pd5TlAs type structure family. Hydrogenation was studied in situ by differential scanning calorimetry (DSC) under 5.0 MPa hydrogen pressure up to 430 °C. Pd0.75Zn0.25, PdCd, PdHg, Pd2Sn, Pd5Pb3, Pd13Pb9, Pd3As, Pd20Sb7, Pd8Sb3, Pd5Sb2, PdSb, Pd5Bi2, Pd17Se15, Pd4Se, Pd5TlAs, Pd5CdSe, Pd5CdAs, Pd5HgSe, Pd5InAs, Pd8In2Se and Pd3Bi2Se2 do not show any sign of hydrogen uptake according to DSC and X-ray diffraction. For Pd3Sn and Pd3Pb a significant hydrogen uptake with unit cell volume increases of 0.4 and 0.6 %, respectively, with a retained structure type of the parent intermetallic was observed. Hydrogenation of Pd5InSe yields Pd3InH≈0.9 and a mixture of palladium selenides. Thermal analysis experiments in helium and in hydrogen atmosphere show that this is a multistep reaction with a decomposition of Pd5InSe to Pd3In and a liquid phase and subsequent hydrogenation of Pd3In.

Keywords: hydrogenation; in situ; metal hydrides; palladium; thermal analysis

Dedicated to: Professor Wolfgang Jeitschko on the occasion of his 80th birthday.

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About the article

Corresponding author: Holger Kohlmann, Inorganic Chemistry, Leipzig University, Johannisallee 29, 04103 Leipzig, Germany, Fax: +49 341 9736199, E-mail:


Received: 2016-01-03

Accepted: 2016-01-22

Published Online: 2016-03-24

Published in Print: 2016-05-01


Citation Information: Zeitschrift für Naturforschung B, Volume 71, Issue 5, Pages 503–508, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2016-0003.

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