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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences


IMPACT FACTOR 2018: 0.961

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1865-7117
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Volume 72, Issue 10

Issues

Syntheses, crystal structures and DNA-binding activities of divalent Fe, Cu, Zn and Cd complexes with 4′-(furan-2-yl)-2,2′:6′,2″-terpyridine

Wei-Wei Fu
  • Corresponding author
  • Key Laboratory of Functional Organometallic Materials of Hunan Province College, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China
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  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Dan Peng
  • Key Laboratory of Functional Organometallic Materials of Hunan Province College, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Ya-Qian Li
  • Key Laboratory of Functional Organometallic Materials of Hunan Province College, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Jing-Run Shen
  • Key Laboratory of Functional Organometallic Materials of Hunan Province College, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Shuang-Hui Li
  • Key Laboratory of Functional Organometallic Materials of Hunan Province College, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2017-09-26 | DOI: https://doi.org/10.1515/znb-2017-0041

Abstract

Five coordination complexes [Fe(ftpy)2](ClO4)2·(H2O)2 (1), [Cu(ftpy)(NO3)(H2O)](NO3) (2), [Cu(ftpy)2]2(ClO4)4·(C2H5OH) (3), [Zn(ftpy)2]·(ClO4)2·(H2O)1.5 (4) and [Cd(ftpy)2]2(ClO4)4·(C2H5OH) (5) (ftpy=4′-(furan-2-yl)-2,2′:6′,2′-terpyridine) have been synthesized and characterized by IR, elemental analysis and single-crystal X-ray diffraction. With the exception of 4, all complexes adopt normal homoleptic [M(ftpy)2]2+ motifs. In the crystal, both hydrogen bonds and face-to-face interactions between furyl and pyridyl rings facilitate the construction of three-dimensional networks. The DNA-binding activities of the five complexes have been investigated by fluorescence emission titration at room temperature suggesting an intercalative mode for 1–3 with a relative order, 3>2>1, and a combined static and dynamic mode for 4 and 5.

This article offers supplementary material which is provided at the end of the article.

Keywords: coordination complex; crystal structure; DNA binding; terpyridine

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About the article

Received: 2017-02-10

Accepted: 2017-06-02

Published Online: 2017-09-26

Published in Print: 2017-09-26


Citation Information: Zeitschrift für Naturforschung B, Volume 72, Issue 10, Pages 687–695, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2017-0041.

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