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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences


IMPACT FACTOR 2018: 0.961

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1865-7117
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Volume 72, Issue 10

Issues

Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamates

Gustavo A. Echeverría
  • Facultad de Ciencias Exactas, Departamento de Física and Instituto IFLP (CONICET- CCT-La Plata), Universidad Nacional de La Plata, 1900-La Plata, Argentina
  • Other articles by this author:
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/ Oscar E. Piro
  • Facultad de Ciencias Exactas, Departamento de Física and Instituto IFLP (CONICET- CCT-La Plata), Universidad Nacional de La Plata, 1900-La Plata, Argentina
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Beatriz S. Parajón-Costa
  • Facultad de Ciencias Exactas, Centro de Química Inorgánica (CEQUINOR/CONICET- CCT-La Plata, UNLP), Universidad Nacional de La Plata, Bvd. 120, N° 1465, 1900-La Plata, Argentina
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/ Enrique J. Baran
  • Corresponding author
  • Facultad de Ciencias Exactas, Centro de Química Inorgánica (CEQUINOR/CONICET- CCT-La Plata, UNLP), Universidad Nacional de La Plata, Bvd. 120, N° 1465, 1900-La Plata, Argentina
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Published Online: 2017-09-29 | DOI: https://doi.org/10.1515/znb-2017-0116

Abstract

Cadmium and lead(II) acesulfamate, Cd(C4H4NO4S)2·2H2O and Pb(C4H4NO4S)2, were prepared by the reaction of acesulfamic acid and the respective metal carbonates in aqueous solution, and characterized by elemental analysis. Their crystal structures were determined by single crystal X-ray diffraction methods. The Cd(II) compound crystallizes in the monoclinic space group P21/c with Z=4 and the corresponding Pb(II) salt in the triclinic space group P1̅ with Z=2. In both salts, acesulfamate acts both as a bi-dentate ligand through its nitrogen and carbonyl oxygen atoms and also as a mono-dentate ligand through this same oxygen atom, giving rise to polymeric structures; in the Pb(II) salt the ligand also binds the cation through its sulfoxido oxygen atoms. The FTIR spectra of the compounds were recorded and are briefly discussed. Some comparisons with other related acesulfamate and saccharinate complexes are made.

Keywords: cadmium acesulfamate; crystal structures; FTIR spectra; lead(II) acesulfamate; synthesis

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About the article

Received: 2017-06-28

Accepted: 2017-08-18

Published Online: 2017-09-29

Published in Print: 2017-09-26


Citation Information: Zeitschrift für Naturforschung B, Volume 72, Issue 10, Pages 739–745, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2017-0116.

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