Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Zeitschrift für Naturforschung B

A Journal of Chemical Sciences


IMPACT FACTOR 2018: 0.961

CiteScore 2018: 0.91

SCImago Journal Rank (SJR) 2018: 0.263
Source Normalized Impact per Paper (SNIP) 2018: 0.505

Online
ISSN
1865-7117
See all formats and pricing
More options …
Volume 72, Issue 10

Issues

Structure and magnetic properties of Sm2Rh3Sn5 – an intergrowth of TiNiSi- and NdRh2Sn4-related slabs

Birgit Heying
  • Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Jutta Kösters
  • Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Rolf-Dieter Hoffmann
  • Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Lukas Heletta
  • Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Rainer Pöttgen
  • Corresponding author
  • Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2017-09-23 | DOI: https://doi.org/10.1515/znb-2017-0127

Abstract

The stannide Sm2Rh3Sn5 was obtained by arc-melting of the elements and subsequent annealing at 1070 K in a silica tube. Sm2Rh3Sn5 crystallizes with the orthorhombic Y2Rh3Sn5 type structure, space group Cmc21, Z=4: a=444.46(8), b=2636.2(4), c=718.3(1) pm, wR=0.0711, 1761 F2 values and 61 variables. The three crystallographically independent rhodium atoms show tricapped trigonal prismatic coordination by samarium and tin atoms. Sm2Rh3Sn5 can be considered as a simple 1:1 intergrowth structure of TiNiSi- and NdRh2Sn4-related slabs of compositions SmRhSn and SmRh2Sn4. Temperature dependent magnetic susceptibility data revealed van Vleck type behavior caused by the proximity of the exited 6H7/2 state to the 6H5/2 ground state of Sm3+, and an antiferromagnetic ordering occurs at TN=3.5(5) K.

Keywords: intermetallics; magnetic properties; samarium; stannide

References

  • [1]

    Y. P. Yarmolyuk, L. G. Akselrud, E. I. Gladyshevskii, Sov. Phys. Crystallogr. 1977, 22, 358.Google Scholar

  • [2]

    L. G. Akselrud, Y. P. Yarmolyuk, E. I. Gladyshevskii, Sov. Phys. Crystallogr. 1977, 22, 492.Google Scholar

  • [3]

    B. Chabot, E. Parthé, J. Less-Common Met. 1985, 106, 53.CrossrefGoogle Scholar

  • [4]

    M. Méot-Meyer, G. Venturini, B. Malaman, J. Steinmetz, B. Roques, Mater. Res. Bull. 1984, 19, 1181.CrossrefGoogle Scholar

  • [5]

    R. Pöttgen, A. Lang, R.-D. Hoffmann, B. Künnen, G. Kotzyba, R. Müllmann, B. D. Mosel, C. Rosenhahn, Z. Kristallogr. 1999, 214, 143.Google Scholar

  • [6]

    Ya. V. Galadzhun, R.-D. Hoffmann, R. Pöttgen, M. Adam, J. Solid State Chem. 1999, 148, 425.CrossrefGoogle Scholar

  • [7]

    P. Villars, K. Cenzual, Pearson’s Crystal Data: Crystal Structure Database for Inorganic Compounds (release 2016/17), ASM International®, Materials Park, Ohio (USA) 2016.Google Scholar

  • [8]

    N. G. Patil, S. Ramakrishnan, Phys. Rev. B 1999, 59, 12054.CrossrefGoogle Scholar

  • [9]

    M. Gamża, R. Gumeniuk, U. Burkhardt, W. Schnelle, H. Rosner, A. Leithe-Jasper, A. Ślebarski, Phys. Rev. B 2017, 95, 165142.CrossrefGoogle Scholar

  • [10]

    E. L. Thomas, M. S. Kim, D. A. Sokolov, M. C. Bennett, M. C. Aronson, J. Y. Chan, J. Solid State Chem. 2007, 180, 2356.CrossrefGoogle Scholar

  • [11]

    C. P. Sebastian, J. Salvador, J. B. Martin, M. G. Kanatzidis, Inorg. Chem. 2010, 49, 10468.CrossrefGoogle Scholar

  • [12]

    L. Piraux, E. Grivei, B. Chevalier, P. Dodor, E. Marquesteaut, J. Etourneau, J. Magn. Magn. Mater. 1993, 128, 313.CrossrefGoogle Scholar

  • [13]

    J.-C. Griveau, E. Colineau, D. Bouëxiere, K. Gofryk, T. Klimczuk, J. Rebizant, J. Alloys Compd. 2013, 576, 409.CrossrefGoogle Scholar

  • [14]

    R. Pöttgen, Th. Gulden, A. Simon, GIT Labor-Fachzeitschrift 1999, 43, 133.Google Scholar

  • [15]

    K. Yvon, W. Jeitschko, E. Parthé, J. Appl. Crystallogr. 1977, 10, 73.CrossrefGoogle Scholar

  • [16]

    V. Petříček, M. Dušek, L. Palatinus, Z. Kristallogr. 2014, 229, 345.Google Scholar

  • [17]

    E. Parthé, L. Gelato, B. Chabot, M. Penzo, K. Cenzual, R. Gladyshevskii, TYPIXStandardized Data and Crystal Chemical Characterization of Inorganic Structure Types. Gmelin Handbook of Inorganic and Organometallic Chemistry, 8th edition, Springer, Berlin, 1993.Google Scholar

  • [18]

    R. Pöttgen, D. Johrendt, Intermetallics – Synthesis, Structure, Function, De Gruyter, Berlin, 2014.Google Scholar

  • [19]

    C. B. Shoemaker, D. P. Shoemaker, Acta Crystallogr. 1965, 18, 900.CrossrefGoogle Scholar

  • [20]

    A. E. Dwight, W. C. Harper, C. W. Kimball, J. Less-Common Met. 1973, 30, 1.CrossrefGoogle Scholar

  • [21]

    R. Mishra, R. Pöttgen, R.-D. Hoffmann, H. Trill, B. D. Mosel, H. Piotrowski, M. F. Zumdick, Z. Naturforsch. 2001, 56b, 589.Google Scholar

  • [22]

    J. F. Riecken, G. Heymann, T. Soltner, R.-D. Hoffmann, H. Huppertz, D. Johrendt, R. Pöttgen, Z. Naturforsch. 2005, 60b, 821.Google Scholar

  • [23]

    M. Méot Meyer, G. Venturini, B. Malaman, B. Roques, Mater. Res. Bull. 1985, 20, 913.CrossrefGoogle Scholar

  • [24]

    S. Andersson, Angew. Chem. 1983, 95, 67.Google Scholar

  • [25]

    E. Parthé, B. Chabot, in Handbook on the Physics and Chemistry of Rare Earths, Vol. 6 (Eds.: K. A. Gschneidner, Jr., L. Eyring), North-Holland, Amsterdam, 1984, p. 113.Google Scholar

  • [26]

    K. Cenzual, E. Parthé, Acta Crystallogr. 1984, C40, 1127.Google Scholar

  • [27]

    E. Parthé, B. Chabot, K. Cenzual, Chimia 1985, 39, 164.Google Scholar

  • [28]

    E. Parthé, Elements of Inorganic Structural Chemistry, Pöge, Leipzig, 1990.Google Scholar

  • [29]

    Y. P. Yarmolyuk, L. A. Lysenko, E. I. Gladyshevskii, Dopov. Akad. Nauk Ukr. RSR, Ser. A 1975, 279.Google Scholar

  • [30]

    D. Voßwinkel, S. F. Matar, R. Pöttgen, Monatsh. Chem. 2015, 146, 1375.CrossrefGoogle Scholar

  • [31]

    J. Emsley, The Elements, Oxford University Press, Oxford, 1999.Google Scholar

  • [32]

    D. Niepmann, R. Pöttgen, B. Künnen, G. Kotzyba, C. Rosenhahn, B. D. Mosel, Chem. Mater. 1999, 11, 1597.CrossrefGoogle Scholar

  • [33]

    D. Niepmann, R. Pöttgen, K. M. Poduska, F. J. DiSalvo, H. Trill, B. D. Mosel, Z. Naturforsch. 2001, 56b, 1.Google Scholar

  • [34]

    J. Donohue, The Structures of the Elements, Wiley, New York, 1974.Google Scholar

  • [35]

    T. Harmening, W. Hermes, M. Eul, F. M. Schappacher, R. Pöttgen, Z. Kristallogr. 2009, 224, 351.Google Scholar

  • [36]

    J. H. van Vleck, The Theory of Electric and Magnetic Susceptibilities, Clarendon Press, Oxford, 1932.Google Scholar

  • [37]

    H. C. Hamaker, L. D. Woolf, H. P. MacKay, Z. Fisk, M. B. Maple, Solid State Commun. 1979, 32, 289.CrossrefGoogle Scholar

  • [38]

    H. Lueken, Magnetochemie, Teubner Studienbücher Chemie, Leipzig, 1999.Google Scholar

  • [39]

    A. M. Stewart, Phys. Rev. B 1972, 6, 1985.CrossrefGoogle Scholar

  • [40]

    S. Seidel, O. Niehaus, S. F. Matar, O. Janka, B. Gerke, U. C. Rodewald, R. Pöttgen, Z. Naturforsch. 2014, 69b, 1105.Google Scholar

  • [41]

    F. Eustermann, M. Eilers-Rethwisch, K. Renner, R.-D. Hoffmann, R. Pöttgen, O. Janka, Z. Naturforsch. 2017, 72b, in press. DOI: 10.1515/znb-2017-0123Google Scholar

About the article

Received: 2017-08-01

Accepted: 2017-08-09

Published Online: 2017-09-23

Published in Print: 2017-09-26


Citation Information: Zeitschrift für Naturforschung B, Volume 72, Issue 10, Pages 753–758, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2017-0127.

Export Citation

©2017 Walter de Gruyter GmbH, Berlin/Boston.Get Permission

Comments (0)

Please log in or register to comment.
Log in