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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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1865-7117
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Volume 72, Issue 6 (May 2017)

Issues

Two new organic-selenate salts: syntheses and crystal structures of bis(di-iso-propylammonium) selenate and di-n-butylammonium hydrogenoselenate

Waly Diallo
  • Corresponding author
  • Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Sénégal
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  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Libasse Diop
  • Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Sénégal
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Cheikh Abdoul Khadir Diop
  • Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Sénégal
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  • De Gruyter OnlineGoogle Scholar
/ Laurent Plasseraud
  • Corresponding author
  • ICMUB UMR CNRS 6302, Université de Bourgogne Franche-Comté, Faculté des Sciences, 9 avenue Alain Savary, F-2100 Dijon, France
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/ Hélène Cattey
  • ICMUB UMR CNRS 6302, Université de Bourgogne Franche-Comté, Faculté des Sciences, 9 avenue Alain Savary, F-2100 Dijon, France
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Published Online: 2017-05-17 | DOI: https://doi.org/10.1515/znb-2017-0032

Abstract

Two new dialkyammonium selenate salts [i-Pr2NH2]2[SeO4] (1) and [n-Bu2NH2][HSeO4] (2) have been isolated and characterized by single-crystal X-ray diffraction. Salt 1 crystallizes in the monoclinic system, space group P21/n with a=8.7190(5), b=8.8500(4), c=22.5953(9) Å, β=94.6290(17)°, V=1737.84(14) Å3 and Z=4. Salt 2 crystallizes in the monoclinic system space group P21/n with a=10.9328(9), b=8.1700(6), c=13.8095(11) Å, β=97.130(3)°, V=1223.94(17) Å3 and Z=4. In both salts, dialkylammonium cations and selenate anions are connected through NH···O and OH···O hydrogen bonds. In the crystal structure, 1 and 2 are organized in layer-like arrangements. Structural characterizations were completed by infrared and 1H, 13C{1H} and 77Se NMR spectroscopy and elemental analysis which corroborate the X-ray elucidations.

This article offers supplementary material which is provided at the end of the article.

Keywords: dialkylammonium cation; hydrogen bonding network; NMR; organic-selenate salt; X-ray crystallography

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About the article

Received: 2017-02-22

Accepted: 2017-03-31

Published Online: 2017-05-17

Published in Print: 2017-05-24


Citation Information: Zeitschrift für Naturforschung B, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2017-0032.

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