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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences


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1865-7117
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Volume 72, Issue 8

Issues

Synthesis and crystal structures of non-symmetric 1,3-di(alkyloxy)imidazolium salts

Markus Jochriem / Christian G. Kirchler / Gerhard Laus
  • Corresponding author
  • Faculty of Chemistry and Pharmacy, University of Innsbruck, 6020 Innsbruck, Austria, Fax: +43 512 507 57099
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/ Klaus Wurst / Holger Kopacka / Thomas Müller / Herwig Schottenberger
Published Online: 2017-07-27 | DOI: https://doi.org/10.1515/znb-2017-0089

Abstract

A series of non-symmetric 1,3-di(alkyloxy)imidazolium salts were synthesized by stepwise alkylation of 1-hydroxyimidazole-3-oxide. The quaternary salts were subsequently functionalized by bromination in 2-position. A 2-azidoimidazolium salt and an imidazoline-2-thione were prepared exemplarily. Crystal structures of two 2-bromo-1-alkyloxy-3-methyloxyimidazolium tribromides and a mercury(II)-thione complex have been determined by X-ray diffraction.

Keywords: imidazolium salt; ionic liquid; mercury; thione; tribromide

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About the article

Received: 2017-05-31

Accepted: 2017-06-29

Published Online: 2017-07-27

Published in Print: 2017-08-28


Citation Information: Zeitschrift für Naturforschung B, Volume 72, Issue 8, Pages 617–626, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2017-0089.

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