Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Zeitschrift für Naturforschung B

A Journal of Chemical Sciences


IMPACT FACTOR 2018: 0.961

CiteScore 2018: 0.91

SCImago Journal Rank (SJR) 2018: 0.263
Source Normalized Impact per Paper (SNIP) 2018: 0.505

Online
ISSN
1865-7117
See all formats and pricing
More options …
Volume 73, Issue 11

Issues

Cationic tri(ferrocenecarbonitrile)silver(I)

Frank Strehler
  • Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry, D-09107 Chemnitz, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Tobias Rüffer
  • Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry, D-09107 Chemnitz, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Julian Noll
  • Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry, D-09107 Chemnitz, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Dieter Schaarschmidt
  • Universität Hamburg, Institut für Anorganische Chemie, Martin-Luther-King-Platz 6, 20146 Hamburg, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Alexander Hildebrandt
  • Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry, D-09107 Chemnitz, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Heinrich Lang
  • Corresponding author
  • Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry, D-09107 Chemnitz, Germany, Tel. +49 (0)371 531 21210, Fax +49 (0)371 531 21219
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2018-08-30 | DOI: https://doi.org/10.1515/znb-2018-0090

Abstract

The synthesis of the tri-coordinated ferrocenecarbonitrile silver(I) complex [Ag(N≡CFc)3]OTf (3) is reported. Its electrochemical behavior shows that the three ferrocenyl units are oxidized in a very close potential range. In addition, the molecular structure of 3 in the solid state is discussed, showing that silver(I) is exclusively coordinated by three ferrocenecarbonitrile molecules.

This article offers supplementary material which is provided at the end of the article.

Keywords: electrochemistry; ferrocenecarbonitrile; silver; solid state structure; trigonal coordination

Dedicated to: Professor Bernt Krebs on the occasion of his 80th birthday.

References

  • [1]

    N. Dowling, P. M. Henry, Inorg. Chem. 1982, 21, 4088.CrossrefGoogle Scholar

  • [2]

    W. Henke, Liebigs Ann. Chem. 1858, 106, 280.CrossrefGoogle Scholar

  • [3]

    R. A. Michelin, M. Mozzon, R. Bertani, Coord. Chem. Rev. 1996, 147, 299.CrossrefGoogle Scholar

  • [4]

    B. N. Storhoff, H. C. Lewis Jr., Coord. Chem. Rev. 1977, 23, 1.CrossrefGoogle Scholar

  • [5]

    M. L. Kuznetsov, Russ. Chem. Rev. 2002, 71, 265.CrossrefGoogle Scholar

  • [6]

    N. A. Bokach, V. Y. Kukushkin, Russ. Chem. Rev. 2005, 74, 153.CrossrefGoogle Scholar

  • [7]

    S. F. Rach, F. E. Kühn, Chem. Rev. 2009, 109, 2061.CrossrefGoogle Scholar

  • [8]

    F. A. Cotton, F. E. Kühn, Inorg. Chim. Acta 1996, 252, 257.CrossrefGoogle Scholar

  • [9]

    F. A. Cotton, L. M. Daniels, S. C. Haefner, F. E. Ku, Inorg. Chim. Acta 1999, 287, 159.CrossrefGoogle Scholar

  • [10]

    A. Bacchi, D. Belli Dell’ Amico, F. Calderazzo, L. Labella, G. Pelizzi, F. Marchetti, S. Samaritani, Inorg. Chim. Acta 2010, 363, 2467.CrossrefGoogle Scholar

  • [11]

    T. M. Pappenfus, J. R. Burney, K. A. McGee, G. G. W. Lee, L. R. Jarvis, D. P. Ekerholm, M. Farah, L. I. Smith, L. M. Hinkle, K. R. Mann, Inorg. Chim. Acta 2010, 363, 3214.CrossrefGoogle Scholar

  • [12]

    M. T. Mock, R. G. Potter, M. J. O’Hagan, D. M. Camaioni, W. G. Dougherty, W. S. Kassel, D. L. DuBois, Inorg. Chim. Acta 2011, 50, 11914.CrossrefGoogle Scholar

  • [13]

    K. Born, P. Comba, M. Kerscher, G. Linti, H. Pritzkow, H. Rohwer, Dalton Trans. 2009, 362.Google Scholar

  • [14]

    S. Liang, H. Wang, T. Deb, J. L. Petersen, G. T. Yee, M. P. Jensen, Inorg. Chem. 2012, 51, 12707.CrossrefGoogle Scholar

  • [15]

    R. T. Henriques, E. Herdtweck, F. E. Kühn, A. D. Lopes, C. C. Romão, J. Chem. Soc., Dalton Trans. 1998, 1293.Google Scholar

  • [16]

    L. Becker, F. Strehler, M. Korb, P. Arndt, A. Spannenberg, W. Baumann, H. Lang, U. Rosenthal, Chem. Eur. J. 2014, 20, 3061.CrossrefGoogle Scholar

  • [17]

    R. Buschbeck, P. J. Low, H. Lang, Coord. Chem. Rev. 2011, 255, 241.CrossrefGoogle Scholar

  • [18]

    B. v. Ahsen, B. Bley, S. Proemmel, R. Wartchow, H. Willner, F. Aubke, Z. Anorg. Allg. Chem. 1998, 624, 1225.CrossrefGoogle Scholar

  • [19]

    A. Sen, Acc. Chem. Res. 1988, 21, 421.CrossrefGoogle Scholar

  • [20]

    T. Haselwander, W. Heitz, Macromol. Chem. Phys. 1996, 197, 3435.CrossrefGoogle Scholar

  • [21]

    T. Kealy, P. Pauson, Nature 1951, 168, 1039.Google Scholar

  • [22]

    K. Aghoramurthy, J. Sci. Ind. Res. 1956, 15B, 11.Google Scholar

  • [23]

    P. Graham, R. Lindsey, J. Am. Chem. Soc. 1957, 72, 3416.Google Scholar

  • [24]

    N. Dowling, P. Henry, N. Lewis, H. Taube, Inorg. Chem. 1981, 20, 2345.CrossrefGoogle Scholar

  • [25]

    K. Handlir, I. Pavlik, Vysoka Skola Chem. Technol. 1965, 1, 13.Google Scholar

  • [26]

    J.-L. Fillaut, N. N. Dua, F. Geneste, L. Toupet, S. Sinbandhit, J. Organomet. Chem. 2006, 691, 5610.CrossrefGoogle Scholar

  • [27]

    H. Helten, M. Beckmann, G. Schnakenburg, R. Streubel, Eur. J. Inorg. Chem. 2010, 2337.Google Scholar

  • [28]

    F. Strehler, A. Hildebrandt, M. Korb, T. Rüffer, H. Lang, Orgmetallics 2014, 33, 4279.CrossrefGoogle Scholar

  • [29]

    F. Strehler, M. Korb, E. A. Poppitz, H. Lang, J. Orgmet. Chem. 2015, 786, 1.CrossrefGoogle Scholar

  • [30]

    F. Strehler, A. Hildebrandt, M. Korb, H. Lang, Z. Anorg. Allg. Chem. 2013, 639, 1214.CrossrefGoogle Scholar

  • [31]

    N. Chawdhury, N. J. Long, M. F. Mahon, L. Ooi, P. R. Raithby, S. Rooke, A. J. P. White, D. J. Williams, M. Younus, J. Organomet. Chem. 2004, 689, 840.CrossrefGoogle Scholar

  • [32]

    H. Lang, R. Packheiser, B. Walfort, Organometallics 2006, 25, 1836.CrossrefGoogle Scholar

  • [33]

    A. Kivrak, M. Zora, J. Organomet. Chem. 2007, 692, 2346.CrossrefGoogle Scholar

  • [34]

    K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Theory and Applications in Inorganic Chemistry, Wiley, Weinheim, New York, 2008.Google Scholar

  • [35]

    W. E. Buschmann, J. S. Miller, Chem. Eur. J. 1998, 4, 1731.CrossrefGoogle Scholar

  • [36]

    G. Gritzner, J. Kuta, Pure Appl. Chem. 1984, 56, 461.CrossrefGoogle Scholar

  • [37]

    S. Manahan, R. Iwamoto, J. Electroanal. Chem. 1967, 14, 213.CrossrefGoogle Scholar

  • [38]

    J. R. Aranzaes, M.-C. Daniel, D. Astruc, Can. J. Chem. 2006, 299, 288.Google Scholar

  • [39]

    R. Dronskowski, X.-H. Liu, Acta Crystallogr. C 2003, 59, m243.CrossrefGoogle Scholar

  • [40]

    L. Chiang, C. Yeh, Z. Chan, K.-M. Wang, Y. Chou, J. Chen, J. Wang, J. Y. Lai, Crystal Growth & Design 2008, 8, 470.CrossrefGoogle Scholar

  • [41]

    J. K. Jabor, R. Stößer, N. H. Thong, B. Ziemer, M. Meisel, Angew. Chem. 2007, 119, 6470.CrossrefGoogle Scholar

  • [42]

    A. A. M. Aly, B. Walfort, H. Lang, Z. Kristallogr. NCS 2009, 219, 489.Google Scholar

  • [43]

    M. Korb, J. Mahrholdt, H. Lang, Eur. J. Inorg. Chem. 2017, 2017, 4028.CrossrefGoogle Scholar

  • [44]

    G. R. Fulmer, A. J. M. Miller, N. H. Sherden, H. E. Gottlieb, A. Nudelman, B. M. Stoltz, J. E. Bercaw, K. I. Goldberg, Organometallics 2010, 29, 2176.CrossrefGoogle Scholar

  • [45]

    G. M. Sheldrick, Acta Crystallogr. A 2008, 64, 112.CrossrefGoogle Scholar

  • [46]

    A. Nafady, W. E. Geiger, Organometallics 2008, 27, 5624.CrossrefGoogle Scholar

About the article

Received: 2018-05-16

Accepted: 2018-08-08

Published Online: 2018-08-30

Published in Print: 2018-11-27


Citation Information: Zeitschrift für Naturforschung B, Volume 73, Issue 11, Pages 759–764, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0090.

Export Citation

©2018 Walter de Gruyter GmbH, Berlin/Boston.Get Permission

Supplementary Article Materials

Comments (0)

Please log in or register to comment.
Log in