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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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1865-7117
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Volume 73, Issue 5

Issues

Lanthanide(III) complex metal-organic frameworks with a phenanthroline-carboxylate derivate and 2,5-thiophenedicarboxylate coligand: hydrothermal synthesis, crystal structure, and high thermostability

Zhao Xu
  • School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, P. R. China
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/ Fengqin An
  • School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, P. R. China
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/ Xiaohui Ma
  • School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, P. R. China
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/ Huiliang Zhou
  • Corresponding author
  • School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, P. R. China, Tel.: +86-951-2062004; Fax: +86-951-2062860
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/ Weiming Song
  • School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, P. R. China
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/ Xiangyu Liu
  • Corresponding author
  • School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, P. R. China, Tel.: +86-951-2062004; Fax: +86-951-2062860
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Published Online: 2018-03-24 | DOI: https://doi.org/10.1515/znb-2018-0016

Abstract

Based on 2-(4-carboxyphenyl)imidazo[4,5-f]-1,10-phenanthroline (HNCP) and 2,5-thiophenedicarboxylate (TDC2−) ligands, three new lanthanide-containing (Sm, Nd, and Pr) compounds, [Sm(NCP)(TDC)]n (1), [Nd(NCP)(TDC)]n·2n(H2O)0.5 (2), and [Pr(NCP)(TDC)]n·n(H2O)0.5 (3), have been synthesized using the hydrothermal method and structurally characterized using single-crystal X-ray diffraction. Structural analyses have revealed that compounds 1–3 are 3D isostructural metal-organic frameworks in which the [Ln2(COO)4] dimers can be regarded as 6-connecting nodes, and the TDC2− and NCP ligands are simplified as connectors to achieve the double interspersed 3D networks with the point symbol {412·63}. Thermogravimetric analysis has illustrated that the rigid architecture contributes to superior thermal stability with a thermal decomposition temperature of more than 400°C for the resulting metal-organic frameworks.

Keywords: 2-(4-carboxyphenyl)imidazo[4,5-f]-1,10-phenanthroline; 2,5-thiophenedicarboxylic acid; crystal structure; lanthanide metal-organic frameworks; thermostability

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About the article

aZhao Xu and Fengqin An: These authors contributed equally to this work.


Received: 2018-01-17

Accepted: 2018-02-25

Published Online: 2018-03-24

Published in Print: 2018-05-24


Citation Information: Zeitschrift für Naturforschung B, Volume 73, Issue 5, Pages 311–317, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0016.

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