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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2016: 0.631

SCImago Journal Rank (SJR) 2016: 0.237
Source Normalized Impact per Paper (SNIP) 2016: 0.332

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1865-7117
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Volume 73, Issue 5

Issues

Synthesis, crystal structure and photoluminescence of Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6

Arnd Vogler
  • Corresponding author
  • Institute of Inorganic Chemistry, University of Regensburg, Universitätsstr. 31, 93053 Regensburg, Germany
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/ Michael Bodensteiner
  • Institute of Inorganic Chemistry, University of Regensburg, Universitätsstr. 31, 93053 Regensburg, Germany
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Published Online: 2018-04-13 | DOI: https://doi.org/10.1515/znb-2018-0021

Abstract

The binuclear complex Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6 has been prepared and characterized including the crystal structure. This complex shows, dependent on the conditions, three emissions, which originate from the quinolinolate IL excited state (fluorescence and phosphorescence) and from a Re(I) to 4,4′-bipyridine MLCT state (phosphorescence).

Keywords: 4,4′-bipyridine; 8-quinolinolate; crystal structure; photoluminescence; rhenium(I)

References

About the article

Received: 2018-02-01

Accepted: 2018-03-25

Published Online: 2018-04-13

Published in Print: 2018-05-24


Citation Information: Zeitschrift für Naturforschung B, Volume 73, Issue 5, Pages 319–322, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0021.

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