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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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Volume 73, Issue 5

Issues

Synthesis and characterization of the new tin borate SnB8O11(OH)4

Sandra Schönegger
  • Institut für Allgemeine, Anorganische und Theoretische Chemie, Leopold-Franzens-Universität Innsbruck, Innrain 80–82, A-6020 Innsbruck, Austria
  • Other articles by this author:
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/ Klaus Wurst
  • Institut für Allgemeine, Anorganische und Theoretische Chemie, Leopold-Franzens-Universität Innsbruck, Innrain 80–82, A-6020 Innsbruck, Austria
  • Other articles by this author:
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/ Gunter Heymann
  • Institut für Allgemeine, Anorganische und Theoretische Chemie, Leopold-Franzens-Universität Innsbruck, Innrain 80–82, A-6020 Innsbruck, Austria
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/ Andreas Schaur
  • Institut für Konstruktion und Materialwissenschaften, Leopold-Franzens-Universität Innsbruck, Technikerstraße 13, A-6020 Innsbruck, Austria
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/ Andreas Saxer
  • Institut für Konstruktion und Materialwissenschaften, Leopold-Franzens-Universität Innsbruck, Technikerstraße 13, A-6020 Innsbruck, Austria
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/ Dirk Johrendt
  • Department Chemie, Ludwig-Maximilians-Universität München, Butenandtstraße 5–13, D-81377 München, Germany
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/ Hubert Huppertz
  • Corresponding author
  • Institut für Allgemeine, Anorganische und Theoretische Chemie, Leopold-Franzens-Universität Innsbruck, Innrain 80–82, A-6020 Innsbruck, Austria
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Published Online: 2018-03-20 | DOI: https://doi.org/10.1515/znb-2018-0035

Abstract

A new tin(II) borate with the composition SnB8O11(OH)4 was synthesized by a simple hydrothermal process. It crystallizes in the centrosymmetric monoclinic space group P21/n (no. 14) with the lattice parameters a=790.1(1), b=1402.2(2), c=994.8(1) pm, and β=90.40(5)° (Z=4). The new compound SnB8O11(OH)4 is isotypic to PbB8O11(OH)4 and isostructural to BaB8O11(OH)4. The borate layers are built up from fundamental building blocks (FBBs) with the composition [B8O11(OH)4]2−. Four of these FBBs form a nine-membered ring wherein the Sn2+ cations are located. These boron-oxygen layers are further connected by O–H···O hydrogen bond interactions. The characterization of SnB8O11(OH)4 is based on single-crystal X-ray diffraction data, vibrational spectroscopy, DFT calculations, and thermoanalytical investigations including high temperature powder XRD.

Keywords: borate; hydrothermal synthesis; single-crystal structure determination; tin borate

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About the article

Received: 2018-03-02

Accepted: 2018-03-04

Published Online: 2018-03-20

Published in Print: 2018-05-24


Citation Information: Zeitschrift für Naturforschung B, Volume 73, Issue 5, Pages 337–348, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0035.

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