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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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Volume 73, Issue 5

Issues

Syntheses and crystal structures of ruthenium complexes with bidentate salicylaldiminato and dithiophosphato ligands

Li-Hua Tang
  • Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, P.R. China
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/ Fule Wu
  • Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, P.R. China
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/ Hui Lin
  • Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, P.R. China
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/ Ai-Quan Jia
  • Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, P.R. China
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/ Qian-Feng Zhang
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  • Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, P.R. China, Fax +86-555-2312041
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Published Online: 2018-05-01 | DOI: https://doi.org/10.1515/znb-2018-0045

Abstract

Treatment of the bidentate Schiff base 2-[(2,6-diisopropyl-phenylimino)-methyl]-phenol (HL1) with one equivalent of (Et4N)[RuCl4(MeCN)2] in the presence of triethylamine afforded (Et4N)[RuCl3(κ2-N,O-L1)(MeCN)] (1), which reacted with two equivalents of K[S2P(OiPr)2] to produce a neutral ruthenium(III) complex [Ru(κ2-N,O-L1){η2-S2P(OiPr)2}2] (2) bearing both salicylaldiminato and dithiophosphato ligands. Reactions of the bidentate Schiff bases 2-[(3-chloro-phenylimino)-methyl]-phenol (HL2) and 2-[(2,4,6-trimethyl-phenylimino)-methyl]-phenol (HL3) with one equivalent of [Ru(CO)2Cl2] in the presence of triethylamine led to formation of the corresponding anionic ruthenium(II) carbonyl complexes (Et3NH)[RuCl2(κ2-N,O-L2)(CO)2] (3) and (Et3NH)[RuCl2(κ2-N,O-L3)(CO)2] (4). The molecular structures of complexes 24 have been determined by single-crystal X-ray diffraction.

Keywords: crystal structure; dithiophosphate; ruthenium; salicylaldimine; synthesis

References

  • [1]

    J. B. Binder, I. A. Guzei, R. T. Raines, Adv. Synth. Catal. 2007, 349, 395.CrossrefGoogle Scholar

  • [2]

    B. De Clercq, F. Verpoort, Adv. Synth. Catal. 2002, 344, 639.CrossrefGoogle Scholar

  • [3]

    S. Dayan, N. K. Ozpozan, N. Özdemir, O. Dayan, J. Organomet. Chem. 2014, 770, 21.CrossrefGoogle Scholar

  • [4]

    W-G. Jia, Z-B. Wang, X-T. Zhi, J-Q. Han, Y. Sun, J. Coord. Chem. 2017, 70, 848.CrossrefGoogle Scholar

  • [5]

    B. Allaert, N. Dieltiens, N. Ledoux, C. Vercaemst, P. V. D. Voort, C. V. Stevens, A. Linden, F. Verpoort, J. Mol. Catal. A 2006, 260, 221.CrossrefGoogle Scholar

  • [6]

    M. Hidai, S. Kuwata, Y. Mizobe, Acc. Chem. Res. 2000, 33, 46.CrossrefGoogle Scholar

  • [7]

    M. Yuki, K. Sakata, Y. Hirao, N. Nonoyama, K. Nakajima, Y. Nishibayashi, J. Am. Chem. Soc. 2015, 137, 4173.CrossrefGoogle Scholar

  • [8]

    F. Dahcheh, D. W. Stephan, Organometallics 2013, 32, 5253.CrossrefGoogle Scholar

  • [9]

    A. J. Deeming, C. Forth, G. Hogarth, Transit. Metal Chem. 2006, 31, 42.CrossrefGoogle Scholar

  • [10]

    A. J. Deeming, C. Forth, G. Hogarth, J. Organomet. Chem. 2006, 691, 79.CrossrefGoogle Scholar

  • [11]

    X-Y. Wang, Y. Li, Q. Ma, Q-F. Zhang, Organometallics 2010, 29, 2752.CrossrefGoogle Scholar

  • [12]

    X. Liu, Q-F. Zhang, W-H. Leung, J. Coord. Chem. 2005, 58, 1299.CrossrefGoogle Scholar

  • [13]

    V. K. Jain, V. S. Jakkal, J. Organomet. Chem. 1996, 515, 81.CrossrefGoogle Scholar

  • [14]

    P. U. Jain, P. Munshi, M. G. Walawalkar, S. P. Rath, K. K. Rajak, G. K. Lahiri, Polyhedron 2000, 19, 801.CrossrefGoogle Scholar

  • [15]

    Y. Li, Q. Ma, H-T. Shi, Q. Chen, Q-F. Zhang, Z. Naturforsch. 2011, 66b, 324.Google Scholar

  • [16]

    X-F. Yin, H. Lin, A-Q. Jia, Q. Chen, Q-F. Zhang, J. Coord. Chem. 2013, 66, 3229.CrossrefGoogle Scholar

  • [17]

    C-J. Wang, H. Lin, X. Chen, A-Q. Jia, Q-F. Zhang, Inorg. Chim. Acta 2017, 467, 198.CrossrefGoogle Scholar

  • [18]

    F. Wu, C-J. Wang, H. Lin, A-Q. Jia, Q-F. Zhang, Inorg. Chim. Acta 2018, 471, 718.CrossrefGoogle Scholar

  • [19]

    J. Dehand, J. Rose, Inorg. Chim. Acta 1979, 31, 249.Google Scholar

  • [20]

    P. A. Anderson, G. B. Deacon, K. H. Haarmann, F. R. Keene, T. J. Meyer, D. A. Reitsma, B. W. Skelton, G. F. Strouse, N. C. Thomas, J. A. Treadway, A. H. White, Inorg. Chem. 1995, 34, 6145.CrossrefGoogle Scholar

  • [21]

    G. Das, R. Shukla, S. Mandal, R. Singh, P. K. Bharadwaj, J. van Hall, K. H. Whitmire, Inorg. Chem. 1997, 36, 323.CrossrefGoogle Scholar

  • [22]

    E. I. Hoegberg, J. T. Cassaday, J. Am. Soc. Chem. 1951, 73, 557.CrossrefGoogle Scholar

  • [23]

    SMART, SAINT+ for Windows NT (version 6.02a), Area Detector Control and Integration Software, Bruker AXS Inc., Madison, Wisconsin (USA) 1998.Google Scholar

  • [24]

    G. M. Sheldrick, SADABS, University of Göttingen, Göttingen (Germany) 1996.Google Scholar

  • [25]

    G. M. Sheldrick, SHELXTL-2014/7, Program for Refinement of Crystal Structures, University of Göttingen, Göttingen (Germany) 2014.Google Scholar

  • [26]

    G. M. Sheldrick, Acta Crystallogr. 2008, A64, 112.Google Scholar

  • [27]

    D. Ooyama, T. Kobayashi, K. Shiren, K. Tanaka, J. Organomet. Chem. 2003, 665, 107.CrossrefGoogle Scholar

  • [28]

    Y. Prieto, M. Muñoz, V. Arancibia, M. Valderrama, F. J. Lahoz, M. L. Martín, Polyhedron 2007, 26, 5527.CrossrefGoogle Scholar

  • [29]

    G. P. Chao, X. Xu, H-T. Shi, Q. Chen, Q-F. Zhang, Acta Crystallogr. 2013, E69, m341.Google Scholar

  • [30]

    R. E. Marsh, Acta Crystallogr. 1995, B51, 897.Google Scholar

  • [31]

    N. Ghavale, S. Dey, A. Wadawale, V. K. Jain, J. Organomet. Chem. 2011, 696, 3491.Google Scholar

  • [32]

    Kh. T. Sharipov, Sh. Sh. Daminovo, L. L. Talipova, J. Struct. Chem. 2002, 43, 396.Google Scholar

  • [33]

    Q. H. Hao, X. Yang, F. Jian, X. Wang, I. A. Razak, S. Chantrapromma, H-K. Fun, Acta Crystallogr. 2001, C57, 42.Google Scholar

  • [34]

    J-Q. Wu, L. Pan, N-H. Hu, Y-S. Li, Organometallics 2008, 27, 3840.CrossrefGoogle Scholar

  • [35]

    A. L. Johnson, M. G. Davidson, M. D. Lunn, M. F. Mahon, Eur. J. Inorg. Chem. 2006, 3088.Google Scholar

  • [36]

    O. Diaz, S. Medina, M. Valderrama, F. J. Lahoz, M. L. Martin, J. Chil. Chem. Soc. 2008, 53, 1480.Google Scholar

  • [37]

    Y-F. Xie, H. Zhu, H-T. Shi, A-Q. Jia, Q-F. Zhang, Inorg. Chim. Acta 2015, 428, 147.CrossrefGoogle Scholar

About the article

Received: 2018-02-19

Accepted: 2018-03-30

Published Online: 2018-05-01

Published in Print: 2018-05-24


Citation Information: Zeitschrift für Naturforschung B, Volume 73, Issue 5, Pages 329–335, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0045.

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