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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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Volume 73, Issue 6

Issues

Studying the reactivity of N-2-(2-aminobenzoyl)-N-phenyl-hydrazinecarbothioamide toward some selected carbonyl compounds

Asmaa H. Mohamed
  • Corresponding author
  • Chemistry Department, Faculty of Science, Minia University, El-Minia, A.R. Egypt, Tel.: +20-121115-7193, Fax: +20-86234-2601
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Published Online: 2018-05-29 | DOI: https://doi.org/10.1515/znb-2018-0010

Abstract

The reactivity of N-2-(2-aminobenzoyl)-N-phenylhydrazinecarbothioamide (1) as an electron donor toward several electron-accepting compounds through electron donor-acceptor interaction has been studied. Thus, upon treatment of 1 with either 1,4-naphthoquinone, 2-dicyanomethyleneindan-1,3-dione, or 2,3-dichloro-1,4-naphthoquinone, the reaction proceeds to give thiadiazino[5,4-b]quinazoline, N-phenylcarbamohydrazonothioate, and thiadiazine-5,10-dione, respectively. Also, the reactivity of compound 1 toward some aldehydes and anhydrides was studied. The products were fully characterized by their spectral data. The mechanisms of formation of the products have been rationalized.

This article offers supplementary material which is provided at the end of the article.

Keywords: 2-(2-aminobenzoyl)-N-phenylhydrazinecarbothioamide; aldehydes; anhydrides; CNIND; DMAD; NQ

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About the article

Received: 2018-01-07

Accepted: 2018-04-22

Published Online: 2018-05-29

Published in Print: 2018-06-27


Citation Information: Zeitschrift für Naturforschung B, Volume 73, Issue 6, Pages 399–406, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0010.

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