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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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IMPACT FACTOR 2016: 0.631

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1865-7117
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Volume 73, Issue 6

Issues

Synthesis, structural characterization, and properties of Ag(I) complexes with N-donor ligands

Xiao-Hong Zhu
  • Corresponding author
  • Faculty of Chemical Engineering, Huaiyin Institute of Technology, Huaian 223003, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Xiao-Chun Cheng / Deng-Hao Li / Yun-Hua Qian
Published Online: 2018-05-22 | DOI: https://doi.org/10.1515/znb-2018-0071

Abstract

New silver complex [Ag(pz)(CF3SO3)] (1) was formed by the coordination reaction of AgCF3SO3 with pyrazine (pz) in the presence of 2-[(S)-4-isopropyl-2-oxazolyl] quinoline (L). When AgBF4 was used instead of AgCF3SO3 as the starting material, complex 2 [Ag(L)(CH3CN)](BF4) was obtained. Complexes 1 and 2 are characterized by single-crystal X-ray diffraction, IR spectroscopy and elemental, and thermogravimetric analysis. Complex 1 shows a 3D framework structure with uni-nodal eight-connected (424.64) topology while complex 2 displays a discrete mononuclear structure. The nonlinear optical properties of 2 were investigated.

Keywords: crystal structure; N-donor ligand; nonlinear optical (NLO) property; pyrazine; quinolone; silver (I)

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About the article

Received: 2018-04-15

Accepted: 2018-05-01

Published Online: 2018-05-22

Published in Print: 2018-06-27


Citation Information: Zeitschrift für Naturforschung B, Volume 73, Issue 6, Pages 423–428, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0071.

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