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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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Volume 73, Issue 9

Issues

A zinc(II) coordination polymer containing single- and double-stranded helical chains: synthesis, crystal structure, and thermal and luminescence properties

Fei-Hang Zhang
  • Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Nan-Nan Chai
  • Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Sheng-Chun Chen
  • Corresponding author
  • Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, P.R. China, Fax: +8651986330251
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Ming-Yang He
  • Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Qun Chen
  • Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2018-08-03 | DOI: https://doi.org/10.1515/znb-2018-0105

Abstract

A new zinc(II)-based coordination polymer {[Zn(5-fip)(tdbpy)]·(DMF)}n (1) {5-H2fip=5-fluoroisophthalic acid, tdbpy=4,4′-(2,4,8,10-tetraoxaspiro[5.5]undecane-3,9-diyl)bispyridine, DMF=dimethylformamide} has been solvothermally synthesized and structurally characterized. Single-crystal X-ray diffraction revealed that complex 1 shows a unique two-dimensional network architecture containing single-stranded [Zn(5-fip)]n and double-stranded helical [Zn(tdbpy)]n chains. The thermal and luminescence properties of complex 1 have also been studied.

This article offers supplementary material which is provided at the end of the article.

Keywords: coordination polymer; helical structure; luminescence property; spiro-functionalized ligand; zinc complex

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About the article

Received: 2018-05-23

Accepted: 2018-07-04

Published Online: 2018-08-03

Published in Print: 2018-09-25


Funding Source: National Natural Science Foundation of China

Award identifier / Grant number: 21676030

This work was supported by the National Natural Science Foundation of China (21676030) and a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) and the Advanced Catalytic and Green Manufacturing Collaborative Innovation Center, Changzhou University.


Citation Information: Zeitschrift für Naturforschung B, Volume 73, Issue 9, Pages 655–660, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0105.

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