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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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1865-7117
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Volume 73, Issue 9

Issues

Structures of the diiodine adducts of bis(diisopropylphosphano)methane disulfide and bis(diisopropylphosphano)ethane disulfide

Mark Strey
  • Institute of Inorganic and Analytical Chemistry, Technical University of Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany
  • Other articles by this author:
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/ Peter G. Jones
  • Corresponding author
  • Institute of Inorganic and Analytical Chemistry, Technical University of Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany
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Published Online: 2018-08-29 | DOI: https://doi.org/10.1515/znb-2018-0135

Abstract

The reaction of bis(diisopropylphosphano)methane disulfide with elemental iodine leads to a 1:1 adduct 1 in which only one sulfur atom of the disulfide coordinates to a diiodine molecule. The corresponding reaction of bis(diisopropylphosphano)ethane disulfide with iodine leads to the “standard” 1:2 adduct, in which both sulfur atoms coordinate to diiodine molecules.

Keywords: chalcogenide; diphosphane; iodine; secondary interactions

Dedicated to: Professor Dietmar Stalke on the occasion of his 60th birthday.

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About the article

Received: 2018-06-27

Accepted: 2018-07-05

Published Online: 2018-08-29

Published in Print: 2018-09-25


Citation Information: Zeitschrift für Naturforschung B, Volume 73, Issue 9, Pages 669–672, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0135.

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